Stay positive: catalysis with 1,3,2-diazaphospholenes

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Understanding the thermodynamics of adsorbates on surfaces is central to many (electro)catalysis applications. In first-principles calculations, additional challenges arise when considering charged adsorbates owing to long-range electrostatic interactions ...

Fe-exchanged zeolites are heterogeneous catalysts that can potentially ensure simultaneous conversion of nitrous oxide (N2O) and nitric oxide (NO) using ammonia (NH3) as a selective reducing agent through their selective catalytic reduction reaction (N2O-N ...

Ruthenium(II) complexes with a three-legged piano-stool structure based on an arene ring, an N-heterocyclic carbene (NHC)-carbene ligand with a peracetylated glucose moiety and two chlorides or one bidentate ligand, were prepared and characterized by spect ...

Solid mixtures of ammonia and water, the so-called ammonia hydrates, are thought to be major components of solar and extra-solar icy planets. We present here a thorough characterization of the recently reported high pressure (P)-temperature (T) phase VII o ...

Aedes aegypti can act as a vector for viral pathogens but the mechanism of viral resistance and evolving host-pathogen tolerance are poorly understood. Here the authors structurally characterise a duplicated pair of interacting Toll immunoreceptors and the ...

The emissive properties of two Ru(II) complexes, [Ru(dmbipy)(2)L-1]PF6 (1) and [Ru-2(dmbipy)(4)L-2]PF6 (2), (where L-1 and L-2 are pi-extended phenanthroline-based ligands and dmbipy = 4,4'-dimethyl-2,2'-bipyridine) have been explored for dual ap ...

Transition metal dichalcogenides (TMDs) represent a class of semiconducting two-dimensional (2D) materials with exciting properties. In particular, defects in 2D-TMDs and their molecular interactions with the environment can crucially affect their physical ...

Convergent paired electrosynthesis is an energy-efficient approach in organic synthesis; however, it is limited by the difficulty to match the innate redox properties of reaction partners. Here we use nickel catalysis to cross-couple the two intermediates ...

Aromatic amines are relevant aquatic organic contaminants whose photochemical transformation is affected by dissolved organic matter (DOM). The goal of this study is to elucidate the underlying mechanism of the inhibitory effect of DOM on such reactions. T ...

The hydrolysis of lignocellulose is the first step in saccharide based bio-refining. The recovery of homogeneous acid catalysts imposes great challenges to the feasibility of conventional hydrolysis processes. Herein, we report a strategy to overcome these ...

Stay positive: catalysis with 1,3,2-diazaphospholenes

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Charged Adsorbates on Metallic Surfaces from Periodic to Open Boundary Conditions

N2O Activation and NO Adsorption Control the Simultaneous Conversion of N2O and NO Using NH3 over Fe-ZSM-5

Ruthenium(II)-Arene Complexes with Glycosylated NHC-Carbene Co-Ligands: Synthesis, Hydrolytic Behavior, and Binding to Biological Molecules

Observation of a Plastic Crystal in Water-Ammonia Mixtures under High Pressure and Temperature

Structure and dynamics of Toll immunoreceptor activation in the mosquito Aedes aegypti

Two in One: A Dinuclear Ru(II) Complex for Deep-Red Light-Emitting Electrochemical Cells and as an Electrochemiluminescence Probe for Organophosphorus Pesticides

Super-resolved Optical Mapping of Reactive Sulfur-Vacancies in Two-Dimensional Transition Metal Dichalcogenides

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C–H bonds

Quenching of an Aniline Radical Cation by Dissolved Organic Matter and Phenols: A Laser Flash Photolysis Study

Mechanochemistry-assisted hydrolysis of softwood over stable sulfonated carbon catalysts in a semi-batch process

Computational and theoretical approaches for mechanistic understanding: general discussion