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The photopolymerization of Co(II)/Co(III) complexes for dye-sensitized solar cells (DSSCs) by means of a fast, inexpensive, in situ and inhibition-free process has been examined. We have succeeded in fabricating high-performance DSSCs able to retain a light-to-electricity power conversion efficiency exceeding 6.5% (8.5% at low intensity) after 1800 h of mixed (light on/off, temperature high/low) accelerated aging tests, thus revealing a possible way for the stabilization of these record-holding redox pairs.
Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer
Michael Graetzel, Jacques-Edouard Moser, Etienne Christophe Socie, George Cameron Fish, Aaron Tomas Terpstra