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Femtosecond fluorescence-upconversion studies of aq. [Ru(bpy)3]2+ show a short-lived vibrationally hot emission of the singlet metal-to-ligand charge-transfer state, with an ultrafast intersystem crossing (~ 10 fs) to the triplet state at const. energy (the colors indicate the luminescence intensity). [on SciFinder (R)]
Anne-Clémence Corminboeuf, Jacob Terence Blaskovits