Mass spectrometryMass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a mass spectrum, a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio.
Arctic sea ice declineSea ice in the Arctic has declined in recent decades in area and volume due to climate change. It has been melting more in summer than it refreezes in winter. Global warming, caused by greenhouse gas forcing is responsible for the decline in Arctic sea ice. The decline of sea ice in the Arctic has been accelerating during the early twenty‐first century, with a decline rate of 4.7% per decade (it has declined over 50% since the first satellite records). It is also thought that summertime sea ice will cease to exist sometime during the 21st century.
Greenland ice sheetThe Greenland ice sheet (Grønlands indlandsis, Sermersuaq) is a vast body of ice covering , roughly near 80% of the surface of Greenland. It is sometimes referred to as an ice cap, or under the term inland ice, or its Danish equivalent, indlandsis. The acronym GIS is frequently used in the scientific literature. It is the second largest ice body in the world, after the Antarctic ice sheet. The ice sheet is almost long in a north–south direction, and its greatest width is at a latitude of 77°N, near its northern margin.
Cloud condensation nucleiCloud condensation nuclei (CCNs), also known as cloud seeds, are small particles typically 0.2 μm, or one hundredth the size of a cloud droplet. CCNs are a unique subset of aerosols in the atmosphere on which water vapour condenses. This can affect the radiative properties of clouds and the overall atmosphere. Water requires a non-gaseous surface to make the transition from a vapour to a liquid; this process is called condensation. In the atmosphere of Earth, this surface presents itself as tiny solid or liquid particles called CCNs.
Resolution (mass spectrometry)In mass spectrometry, resolution is a measure of the ability to distinguish two peaks of slightly different mass-to-charge ratios ΔM, in a mass spectrum. There are two different definitions of resolution and resolving power in mass spectrometry. The IUPAC definition for resolution in mass spectrometry is Where a larger resolution indicates a better separation of peaks. This definition is used in a number of mass spectrometry texts. This use is also implied by the term "high-resolution mass spectrometry.
Little Ice AgeThe Little Ice Age (LIA) was a period of regional cooling, particularly pronounced in the North Atlantic region. It was not a true ice age of global extent. The term was introduced into scientific literature by François E. Matthes in 1939. The period has been conventionally defined as extending from the 16th to the 19th centuries, but some experts prefer an alternative timespan from about 1300 to about 1850. The NASA Earth Observatory notes three particularly cold intervals.
Radiative forcingRadiative forcing (or climate forcing) is the change in energy flux in the atmosphere caused by natural or anthropogenic factors of climate change as measured in watts per meter squared. It is a scientific concept used to quantify and compare the external drivers of change to Earth's energy balance. These external drivers are distinguished from climate feedbacks and internal variability, which also influence the direction and magnitude of imbalance. Positive radiative forcing means Earth receives more incoming energy from sunlight than it radiates to space.
Sea iceSea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice, which has an even lower density). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world's sea ice is enclosed within the polar ice packs in the Earth's polar regions: the Arctic ice pack of the Arctic Ocean and the Antarctic ice pack of the Southern Ocean.
GlacierA glacier (USpronˈɡleɪʃər; UKˈɡlæsiər,_ˈgleɪsiər) is a persistent body of dense ice that is constantly moving under its own weight. A glacier forms where the accumulation of snow exceeds its ablation over many years, often centuries. It acquires distinguishing features, such as crevasses and seracs, as it slowly flows and deforms under stresses induced by its weight. As it moves, it abrades rock and debris from its substrate to create landforms such as cirques, moraines, or fjords.
Ion-mobility spectrometry–mass spectrometryIon mobility spectrometry–mass spectrometry (IMS-MS) is an analytical chemistry method that separates gas phase ions based on their interaction with a collision gas and their masses. In the first step, the ions are separated according to their mobility through a buffer gas on a millisecond timescale using an ion mobility spectrometer. The separated ions are then introduced into a mass analyzer in a second step where their mass-to-charge ratios can be determined on a microsecond timescale.
Earth's energy budgetEarth's energy budget accounts for the balance between the energy that Earth receives from the Sun and the energy the Earth loses back into outer space. Smaller energy sources, such as Earth's internal heat, are taken into consideration, but make a tiny contribution compared to solar energy. The energy budget also accounts for how energy moves through the climate system. Because the Sun heats the equatorial tropics more than the polar regions, received solar irradiance is unevenly distributed.
Liquid chromatography–mass spectrometryLiquid chromatography–mass spectrometry (LC–MS) is an analytical chemistry technique that combines the physical separation capabilities of liquid chromatography (or HPLC) with the mass analysis capabilities of mass spectrometry (MS). Coupled chromatography - MS systems are popular in chemical analysis because the individual capabilities of each technique are enhanced synergistically. While liquid chromatography separates mixtures with multiple components, mass spectrometry provides spectral information that may help to identify (or confirm the suspected identity of) each separated component.
Polar amplificationPolar amplification is the phenomenon that any change in the net radiation balance (for example greenhouse intensification) tends to produce a larger change in temperature near the poles than in the planetary average. This is commonly referred to as the ratio of polar warming to tropical warming. On a planet with an atmosphere that can restrict emission of longwave radiation to space (a greenhouse effect), surface temperatures will be warmer than a simple planetary equilibrium temperature calculation would predict.
Time-of-flight mass spectrometryTime-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which an ion's mass-to-charge ratio is determined by a time of flight measurement. Ions are accelerated by an electric field of known strength. This acceleration results in an ion having the same kinetic energy as any other ion that has the same charge. The velocity of the ion depends on the mass-to-charge ratio (heavier ions of the same charge reach lower speeds, although ions with higher charge will also increase in velocity).
Tandem mass spectrometryTandem mass spectrometry, also known as MS/MS or MS2, is a technique in instrumental analysis where two or more mass analyzers are coupled together using an additional reaction step to increase their abilities to analyse chemical samples. A common use of tandem MS is the analysis of biomolecules, such as proteins and peptides. The molecules of a given sample are ionized and the first spectrometer (designated MS1) separates these ions by their mass-to-charge ratio (often given as m/z or m/Q).
Proton-transfer-reaction mass spectrometryProton-transfer-reaction mass spectrometry (PTR-MS) is an analytical chemistry technique that uses gas phase hydronium reagent ions which are produced in an ion source. PTR-MS is used for online monitoring of volatile organic compounds (VOCs) in ambient air and was developed in 1995 by scientists at the Institut für Ionenphysik at the Leopold-Franzens University in Innsbruck, Austria. A PTR-MS instrument consists of an ion source that is directly connected to a drift tube (in contrast to SIFT-MS no mass filter is interconnected) and an analyzing system (quadrupole mass analyzer or time-of-flight mass spectrometer).
Ice–albedo feedbackIce–albedo feedback is a positive feedback climate process where a change in the area of ice caps, glaciers, and sea ice alters the albedo and surface temperature of a planet. Ice is very reflective, therefore it reflects far more solar energy back to space than the other types of land area or open water. Ice–albedo feedback plays an important role in global climate change. For instance, at higher latitudes, warmer temperatures melt the ice sheets.
ClimateClimate is the long-term weather pattern in a region, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteorological variables that are commonly measured are temperature, humidity, atmospheric pressure, wind, and precipitation. In a broader sense, climate is the state of the components of the climate system, including the atmosphere, hydrosphere, cryosphere, lithosphere and biosphere and the interactions between them.
Secondary ion mass spectrometrySecondary-ion mass spectrometry (SIMS) is a technique used to analyze the composition of solid surfaces and thin films by sputtering the surface of the specimen with a focused primary ion beam and collecting and analyzing ejected secondary ions. The mass/charge ratios of these secondary ions are measured with a mass spectrometer to determine the elemental, isotopic, or molecular composition of the surface to a depth of 1 to 2 nm.
Attribution of recent climate changeEfforts to scientifically ascertain and attribute mechanisms responsible for recent global warming and related climate changes on Earth have found that the main driver is elevated levels of greenhouse gases produced by human activities, with natural forces adding variability. The likely range of human-induced surface-level air warming by 2010–2019 compared to levels in 1850–1900 is 0.8 °C to 1.3 °C, with a best estimate of 1.07 °C. This is close to the observed overall warming during that time of 0.9 °C to 1.
