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Herein described is a method for producing a gas separation membrane precursor and optionally a gas separation membrane, in particular for co2 separation, containing a porous single-layer graphene film. the method comprises the following steps: (a) providing a metal foil substrate; (b) preparing a porous single-layer graphene film on the metal foil substrate; (c) depositing a gas-permeable support film on top of the porous single-layer graphene film; (d) applying a layer of transfer release tape on top of the gas-permeable support film; and (e) removing, in particular delaminating, the metal foil substrate to obtain a gas separation membrane precursor. the gas separation membrane can be obtained from the gas separation membrane precursor. also described is a gas separation membrane obtainable by the method according to the invention.