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Influence of Operational Parameters on LSCF and LSF Stability

Related publications (31)

Quantifying mass transport limitations in a microfluidic CO2 electrolyzer with a gas diffusion cathode

A gas diffusion electrode (GDE) based CO2 electrolyzer shows enhanced CO2 transport to the catalyst surface, significantly increasing current density compared to traditional planar immersed electrodes. A two-dimensional model for the cathode side of a micr ...

2024

Reversible photo-electrochemical device for solar hydrogen and power generation

Sophia Haussener, Alexandre Dominique M. Cattry, Saurabh Yuvraj Tembhurne, Matthieu Jonin, Mahendra Patel

A reversible photo-electrochemical device operating under concentrated irradiation could offer a stand-alone solution for producing solar fuel (in photo-driven electrolysis mode) and power (in fuel cell mode). This strategy would present the advantage of h ...

2024

Contrasting Views of the Electric Double Layer in Electrochemical CO2 Reduction: Continuum Models vs Molecular Dynamics

Sophia Haussener, Evan Fair Johnson

In the field of electrochemical CO2 reduction, both continuum models and molecular dynamics (MD) models have been used to understand the electric double layer (EDL). MD often focuses on the region within a few nm of the electrode, while continuum models ca ...

Amer Chemical Soc2024

Electrochemical devices and computer science: water/thermal management of proton exchange membrane fuel cells and electrolyzers in different scales

Hossein Pourrahmani

The current restrictions on the registration of combustion engines in different countries and the harmful impacts of fossil fuels on the environment and human health have motivated decision-makers to use batteries and/or fuel cells as alternatives for comb ...

EPFL2023

Membrane electrode assembly simulation of anion exchange membrane water electrolysis

Jan Van Herle, Zoé Mury, Suhas Nuggehalli Sampathkumar, Khaled Lawand

Anion exchange membrane water electrolysis (AEMWE) offers a green hydrogen production method that eliminates the need for platinum group metals (PGM) as electrocatalysts. This study employs a COMSOL (R) 6.0 model to simulate a 1x1 cm(2) Ni fibre - Raney (R ...

Elsevier2024

Spinel Protective Coatings for Solid Oxide Cell (SOC) Interconnects (ICs)

Samaneh Daviran

Abstract The degradation of metal interconnects (ICs) in Solid Oxide Cells (SOCs) primarily results from chromium (Cr) oxide scale growth on stainless-steel substrates, causing ohmic loss and air-side electrode poisoning by Cr. This thesis addresses these ...

EPFL2024

A pre-fatigue training strategy to stabilize LiCoO2 at high voltage

Lei Zhang, Rui Xia, Kangning Zhao

Layered cathodes are among the most promising cathodes for high-energy-density Li-ion batteries, yet hindered by the structural degradation from both bulk strain and surface oxygen loss at high voltage (above 4.5 V). Herein, we report a pre-fatigue trainin ...

Royal Soc Chemistry2024

Artificial Hydrophilic Organic and Dendrite-Suppressed Inorganic Hybrid Solid Electrolyte Interface Layer for Highly Stable Zinc Anodes

Lei Zhang, Kangning Zhao

Aqueous zinc-ion batteries (AZIBs) have gained significant attentions for their inherent safety and cost-effectiveness. However, challenges, such as dendrite growth and anodic corrosion at the Zn anode, hinder their commercial viability. In this paper, an ...

Amer Chemical Soc2024

An Advanced Alkaline Al-Air Fuel Cell Using L-Ascorbic Acid Interface Layer upon Al Anode via Gradient Anti-corrosion

Pengfei Zhang, Manhui Wei

Al metal is considered as an excellent anode material for metal-air fuel cells thanks to the advantages in terms of capacity and energy density. However, the anodic parasitic corrosion has brought great obstacles to the performance breakthrough of Al-air f ...

AMER CHEMICAL SOC2023

Gas generating membrane-less electrolyser

Demetri Psaltis, Steven Alexandre Schenk, Pooria Hadikhani

Electrolyser including a reactor (2) comprising a housing (4), fluidic channels (6a, 6b, 6c) within the housing, and electrodes (16a, 16c) comprising an anode (16a) and a cathode (16c). The fluidic channels include an inter-electrode channel (6b) arranged ...

2023

Raising the temperature on electrodes for anion exchange membrane electrolysis-activity and stability aspects

Jan Van Herle, Peter Hugh Middleton, Thomas Benjamin Ferriday

The membrane electrode assembly is the powerhouse of the anion exchange membrane water electrolyser (AEMWE), thereby placing a great importance on the associated preparation conditions. This paper investigated how annealing temperature and time impacted ac ...

ELSEVIER2023

Three-dimensional nanoimaging of fuel cell catalyst layers

Vasiliki Tileli, Robin Pierre Alain Girod, Timon Lazaridis

Catalyst layers in proton exchange membrane fuel cells consist of platinum-group-metal nanocatalysts supported on carbon aggregates, forming a porous structure through which an ionomer network percolates. The local structural character of these heterogeneo ...

NATURE PORTFOLIO2023

Readiness evaluation of SOFC-MGT hybrid systems with carbon capture for distributed combined heat and power

Jürg Alexander Schiffmann, Jan Van Herle, Michele Gaffuri, Victoria Xu Hong He

The aggravation of climate change calls for the timely development and implementation of highly efficient, renewable, zero- or negative-emission energy solutions with high technological readiness and feasibility levels. Solid oxide fuel cells (SOFC) consti ...

Elsevier2023

The thermodynamic and life-cycle assessments of a novel charging station for electric vehicles in dynamic and steady-state conditions

Jan Van Herle, Hossein Pourrahmani, Chengzhang Xu

The current study performs the thermodynamic and life-cycle assessments (LCA) of a novel charging station in two system designs. The goal is to design an efficient charging station for electric vehicles with high efficiencies and low environmental impacts ...

Nature Portfolio2023

Fast online diagnosis for solid oxide fuel cells: Optimisation of total harmonic distortion tool for real-system application and reactants starvation identification

Jan Van Herle, Hamza Moussaoui, Gerald Hammerschmid

This study investigates the potential application of total harmonic distortion (THD), as a fast online monitoring tool, to identify the early signs of failure modes in solid oxide fuel cells (SOFC). Indeed, the timely detection and identification of faults ...

ELSEVIER2023

Hybridisation Scenarios of Solid Oxide Fuel Cells, Batteries, and Internal Combustion Engines for Waterborne Transportation

François Maréchal, Daniel Alexander Florez Orrego

The shipping industry was responsible for about 3% of global greenhouse gas (GHG) emissions in 2018. In this context, the International Maritime Organisation (IMO) has established stringent targets to reduce GHG emissions by at least 50% by 2050 compared t ...

Universidad de Las Palmas de Gran Canaria2023

The design and development of anion exchange membranes for hydrogen fuel cells

Xingyu Wu

Hydrogen fuel cells are an essential component of hydrogen economy, which have been advocated as a major path towards the decarbonization of the energy sector. Within the two main types of low-temperature hydrogen fuel cells, anion-exchange membrane fuel c ...

EPFL2023

Decoupling the Contributions of Different Instability Mechanisms to the PEMFC Performance Decay of Non-noble Metal O2-Reduction Catalysts

Vasiliki Tileli, Robin Pierre Alain Girod, Secil Unsal

Non-noble metal catalysts (NNMCs) hold the potential to replace the expensive Pt-based materials currently used to speed up the oxygen reduction reaction (ORR) in proton exchange membrane fuel cell (PEMFC) cathodes, but they feature poor durability that in ...

AMER CHEMICAL SOC2023

Robust Piperidinium-Enriched Polystyrene Ionomers for Anion Exchange Membrane Fuel Cells and Water Electrolyzers

Xile Hu, Fang Song, Nanjun Chen

Durable and efficient anion exchange polyelectrolytes (AEPs) are crucial for the long-term operation of cost-effective anion exchange membrane fuel cells (AEMFCs) and water electrolyzers (AEMWEs). Here, we present a new class of ?-amine-piperidinium-functi ...

AMER CHEMICAL SOC2023

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Vasiliki Tileli, Tzu-Hsien Shen, Robin Pierre Alain Girod

The value of operando and in situ characterization methodologies for understanding electrochemical systems under operation can be inferred from the upsurge of studies that have reported mechanistic insights into electrocatalytic processes based on such mea ...

Amer Chemical Soc2023