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By combining high photon flux and chemical selectivity, X-ray absorption spectroscopy and X-ray magnetic circular dichroism (XMCD) have been used to study the magnetism of CoPt and FePt clusters before and after their transition to the chemically ordered L1(0)-like phase. Compared to the bulk, we find larger magnetic spin and orbital moments of Fe, Co and Pt atoms in nanoalloys. (C) 2014 Elsevier B.V. All rights reserved.