Publication

Scanning electrochemical microscopy determination of hydrogen flux at liquid|liquid interface with potentiometric probe

Hubert Girault
2014
Journal Articles

Abstract

Scanning electrochemical microscopy potentiometric determination of local hydrogen concentration and its flux next to the liquid|liquid interface was demonstrated. This method is based on the shift of open circuit potential of Pt-based reversible hydrogen electrode. The detection system was verified with a system generating hydrogen under galvanostatic conditions. Then, it was applied to aqueous|1,2-dichloroethane interface where hydrogen is produced with decamethylferrocene as electron donor.

Official source

https://infoscience.epfl.ch/entities/publication/e5eb74d0-295c-4538-9de0-1ad29d98913b

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Scanning electrochemical microscopy determination of hydrogen flux at liquid|liquid interface with potentiometric probe

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