Metalation and derivatization of all six dichlorobenzotrifluorides: Site selectivities

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Cross-coupling of two alkyl fragments is an efficient method to produce organic molecules rich in sp(3)-hybridized carbon centres, which are attractive candidate compounds in drug discovery. Enantioselective C(sp(3))-C(sp(3)) coupling is challenging, espec ...

Renewable energy supply and energy storage in a closed materials cycle are the urgent global challenges of the 21st century. Carbon dioxide (CO2) hydrogenation over catalysts is a method to produce synthetic fuels from renewable energy in a CO2 neutral cyc ...

N-formylation of amines with CO2 is base-catalyzed and studies of salt catalysts reveal that the reaction is efficiently catalyzed by "free" floating anions of high basicity, as represented in the cover image. More information can be found in the Full Pape ...

The thesis describes a simple approach for N-formylation of amines with CO2 and hydrosilane reducing agents, the use of organic salts as N-formylation catalysts, their physical properties required for high catalytic activity and their role in the catalytic ...

The alkynylation of radical intermediates has been known since a long time, but had not been broadly applied in synthetic chemistry, in contrast to the alkynylation of either electrophiles or nucleophiles. In the last decade however, it has been intensivel ...

A palladium-catalyzed multicomponent reaction of propargylic amines, alkynyl bromides and cesium hydrogen carbonate to access oxazolidinones is reported. In contrast to previous reports, only a slight excess of cesium hydrogen carbonate is used as a surrog ...

The present invention relates to the removal of carbon dioxide from gases. More particularly, the invention relates to the use of metal-organic frameworks for a selective adsorption of carbon dioxide from a gas. Further, the invention relates to a method f ...

The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...

Aliphatic alkynes and nitriles are privileged motifs in organic chemistry. Therefore, alkynes and nitriles have played a central role for the exploration and development of novel strategies to forge C-C bonds in efficient manner. They are broadly used as v ...

Alkynyl sulfoxides are important building blocks with a unique reactivity in organic chemistry, but only a few reliable methods have been reported to synthesize them. A novel route to access alkynyl sulfoxides is reported herein by using ethynyl benziodoxo ...

Electrochemical reduction of carbon dioxide, using the electricity generated from renewable energy sources, has the potential of rendering a carbon-neutral energy economy. Developing selective, efficient and robust electrocatalysts is the key step towards ...

CONSPECTUS: Ligand development plays an essential role in the advance of homogeneous catalysis. Tridentate, meridionally coordinating ligands, commonly termed pincer ligands, have been established as a privileged class of ligands in catalysis because they ...

Inland waters, including streams and rivers, are active components of the global carbon cycle.Despite the large areal extent of the world’s mountains, the role of mountain streams forglobal carbonfluxes remains elusive. Using recent insights from gas excha ...

Metalation and derivatization of all six dichlorobenzotrifluorides: Site selectivities

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Enantioselective C(sp(3))-C(sp(3)) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

Mechanisms of the Heterogeneously Catalyzed Reaction of CO2 Hydrogenation on Transition Metal Surfaces

Delineation of the Critical Parameters of Salt Catalysts in the N-Formylation of Amines with CO2

Organocatalysts in C-N Bond Forming Reactions of Amines with CO2

Alkynylation of radicals: spotlight on the "Third Way" to transfer triple bonds

Palladium-Catalyzed Carboxy-Alkynylation of Propargylic Amines Using Carbonate Salts as Carbon Dioxide Source

Selective adsorption of carbon dioxide by a metal-organic framework

Mechanistic implications of lanthanum-modification on gold-catalyzed formic acid decomposition under SCR-relevant conditions

Photoredox-Catalyzed Decarboxylation for the Transfer of Alkynes and Nitriles Using Hypervalent Iodine Reagents

Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents

Bimetallic Electrocatalysts for Carbon Dioxide Reduction

Nickamine and Analogous Nickel Pincer Catalysts for Cross-Coupling of Alkyl Halides and Hydrosilylation of Alkenes

Unexpected large evasion fluxes of carbon dioxide from turbulent streams draining the world’s mountains