Publication

Heterogeneous Chemistry of Cl2O and HOCl on Frozen Natural Sea Salt, Recrystallized Sea Salt, KCl and NaCl Solutions at 200 and 215 K

Related publications (31)

Kinetic and mechanistic understanding of chlorite oxidation during chlorination: Optimization of ClO2 pre-oxidation for disinfection byproduct control

Chlorine dioxide (ClO2) applications to drinking water are limited by the formation of chlorite (ClO2-) which is regulated in many countries. However, when ClO2 is used as a pre-oxidant, ClO2- can be oxidized by chlorine during subsequent disinfection. In ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Molecular dynamics simulations of the evaporation of hydrated ions from aqueous solution

Philip Robin Loche

Although important for atmospheric processes and gas-phase catalysis, very little is known about the hydration state of ions in the vapor phase. Here we study the evaporation energetics and kinetics of a chloride ion from liquid water by molecular dynamics ...

NATURE PORTFOLIO2022

Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet

Andreas Osterwalder, Bruno Credidio

We present chemical kinetics measurements of the luminol oxidation chemiluminescence (CL) reaction at the interface between two aqueous solutions, using liquid jet technology. Free-flowing liquid microjets are a relatively recent development that have foun ...

2022

Delayed Hydride Cracking in Irradiated and Unirradiated Zircaloy-2 Cladding

Aaron William Colldeweih

Zirconium alloys used in the nuclear industry are exposed to extreme conditions undergoing high levels of irradiation damage and corrosion. Zircaloy-2 is used as nuclear fuel cladding in boiling water reactors and for the encapsulation of the spallation ta ...

EPFL2022

Anionic character of the conduction band of sodium chloride

Klaus Kern, Abhishek Grewal

The alkali halides are ionic compounds. Each alkali atom donates an electron to a halogen atom, leading to ions with full shells. The valence band is mainly located on halogen atoms, while, in a traditional picture, the conduction band is mainly located on ...

Nature Portfolio2022

Dynamics of cavitation bubbles near granular boundaries

Mohamed Farhat, Armand Baptiste Sieber, Davide Bernardo Preso

We study the dynamics of a cavitation bubble near beds of sand of different grain sizes. We use high-speed imaging to observe the motion of the bubble and the sand for different values of the stand-off parameter gamma (dimensionless bubble-boundary distanc ...

Cambridge University Press2022

Delayed gamma fraction determination in the zero power reactor CROCUS

Pavel Frajtag, Andreas Pautz, Oskari Ville Pakari, Vincent Pierre Lamirand, Tom Mager

Gamma rays are an inextricable part of a nuclear reactor's radiation field, and as such require characterization for dose rate estimations required for the radiation protection of personnel, material choices, and the design of nuclear facilities. Most comm ...

EDP SCIENCES S A2021

Factors affecting the reactivity of slag at early and late ages

Mohsen Ben Haha, Karen Scrivener, Yosra Briki

This study investigates the difference between the reactivity of slag in NaOH solution (w/s = 100) and in cement paste (w/b = 0.4). The reactivity of slag is much higher in NaOH solution than in cement paste. When the NaOH solution is saturated with portla ...

Pergamon-Elsevier Science Ltd2021

Modeling the response of a diamond detector in the zero power reactor CROCUS

Pavel Frajtag, Andreas Pautz, Vincent Pierre Lamirand, Mathieu Hursin, DongHyuk Lee

The present manuscript documents the development of a practical calculation scheme to model the response of a diamond detector in the mixed (neutron and gamma) radiation field of the CROCUS experimental reactor at EPFL. The model is shown to perform reason ...

SPRINGER HEIDELBERG2021

Studies of cold chemistry in crossed and merged neutral beams

Silvia Tanteri

In this thesis we present the design of two setups to study low-energy collisions between neutral species: an electron velocity map imaging for chemi-ionisation reactions and a merged electrostatic guide for polar molecules scattering. In the past few yea ...

EPFL2021

A Hybrid Approach to Neutron Transport with Thermal-hydraulic Feedback for Reactor Transient Analysis

Alexander Aures

Understanding the time-dependent behaviour of a nuclear reactor following an intended or unintended change of the reactor conditions is of crucial importance to the safe operation of nuclear reactors. Safety evaluations of nuclear reactors involve the anal ...

EPFL2021