Publications related to On the stability and necessary electrophoretic mobility of bare oil nanodroplets in water

Related publications (28)

Second harmonic scattering of nanoparticles: A journey into the electrical double layer

In aqueous solutions, a charged surface causes the redistribution of nearby ions. The ion layers formed are known as the electrical double layer (EDL), and are widespread in many systems involving electrochemistry, colloidal science, biomedicine, and energ ...

EPFL2024

Size dependence of second-harmonic scattering from nanoparticles: Disentangling surface and electrostatic contributions

Sylvie Roke, Arianna Marchioro, Bingxin Chu

Polarimetric angle-resolved second-harmonic scattering (AR-SHS) is an all-optical tool enabling the study of unlabeled interfaces of nano-sized particles in an aqueous solution. As the second harmonic signal is modulated by interference between nonlinear c ...

AIP Publishing2023

Modulating the Surface Properties of Lithium Niobate Nanoparticles by Multifunctional Coatings Using Water-in-Oil Microemulsions

Sandrine Gerber, Alessandra Spada, Adrian Stefan Gheata

Inorganic nanoparticles (NPs) have emerged as promising tools in biomedical applications, owing to their inherent physicochemical properties and their ease of functionalization. In all potential applications, the surface functionalization strategy is a key ...

2023

Molecular insights into the electrical double layer of colloidal oxide particles obtained through second harmonic scattering

Marie Bischoff

Photocatalytic applications play an essential role in the search for alternative energy sources and environmental decontamination techniques. It is of fundamental interest to understand on a molecular level the aqueous solid/liquid interface, where photoca ...

EPFL2022

Effects of surface rigidity and metallicity on dielectric properties and ion interactions at aqueous hydrophobic interfaces

Philip Robin Loche

Using classical molecular dynamics simulations, we investigate the dielectric properties at interfaces of water with graphene, graphite, hexane, and water vapor. For graphite, we compare metallic and nonmetallic versions. At the vapor-liquid water and hexa ...

AIP Publishing2022

Electrokinetic, electrochemical, and electrostatic surface potentials of the pristine water liquid-vapor interface

Philip Robin Loche

Although conceptually simple, the air-water interface displays rich behavior and is subject to intense experimental and theoretical investigations. Different definitions of the electrostatic surface potential as well as different calculation methods, each ...

AIP Publishing2022

Charge transfer across C-H center dot center dot center dot O hydrogen bonds stabilizes oil droplets in water

Sylvie Roke, Saranya Pullanchery Sankara Narayanan, Sergey Kulik, Benjamin Rehl

The hydrophobic-water interface plays a key role in biological interactions. However, both the hydrophobic-water interfacial molecular structure and the origin of the negative zeta potential of hydrophobic droplets in water are heavily contested. We report ...

American Association for the Advancement of Science2021

In-situ Investigations on Gold Nanoparticles Stabilization Mechanisms in Biological Environments Containing HSA

Francesco Stellacci, Quy Ong Khac, Antonia Neels, Marianne Liebi

Nanoparticles (NPs) developments advance innovative biomedical applications. However, complex interactions and the low colloidal stability of NPs in biological media restrict their widespread utilization. The influence of NPs properties on the colloidal st ...

WILEY-V C H VERLAG GMBH2021

Porous granules by freeze granulation of Pickering emulsions stabilized with halloysite particles

Paul Bowen

Pickering emulsions stabilized with a natural silicate mineral, halloysite, were dried by freeze granulation in order to prepare porous granules. Different formulations were studied, by varying the pH of the suspension, the ionic strength and with the addi ...

ELSEVIER2020

Self-Assembly at Water Nanodroplet Interfaces Quantified with Nonlinear Light Scattering

Sylvie Roke, Nikolay Smolentsev

The interfaces of water micro- and nanodroplets drive environmental, medical, catalytic, biological, and chemical biphasic processes. The interfacial droplet structure and electrostatics greatly determine the reactivity and efficiency of these processes. D ...

AMER CHEMICAL SOC2020

Self-Propulsion of Active Colloids via Ion Release: Theory and Experiments

Ignacio Pagonabarraga Mora

We study the self-propulsion of a charged colloidal particle that releases ionic species using theory and experiments. We relax the assumptions of thin Debye length and weak nonequilibrium effects assumed in classical phoretic models. This leads to a numbe ...

2020

Specific Ion Effects at the Interface of Nanometer-Sized Droplets in Water: Structure and Stability

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

The interaction of ions with interfaces influences numerous processes in chemistry, physics, and biology, while different ion species behave differently at hydrophobic or hydrophilic interfaces. Despite its importance, ion specificity and its relation to s ...

2019

Molecular Level Interfacial Studies of Nanoemulsions: Surface Structure, Specific Ion Effects and Stability

Evangelia Zdrali

This thesis is a study on the molecular structure of the interface of nanometer-sized oil droplets dispersed in water, a system known as oil-in-water nanoemulsion. The motivation for this research is the large significance of the interfacial nanostructures ...

EPFL2019

Mechanisms of fluorescence quenching in prototypical aggregation-induced emission systems: excited state dynamics with TD-DFTB

Anne-Clémence Corminboeuf, Antonio Prlj, Kun-Han Lin, Daniel Hollas

A recent implementation of time-dependent tight-binding density functional theory is employed in excited state molecular dynamics for the investigation of the fluorescence quenching mechanism in 3 prototypical aggregation-induced emission systems. An asses ...

ROYAL SOC CHEMISTRY2019

Fluorinated surfactants in droplet-based microfluidics: Influence of their composition on the properties of emulsion drops

Gianluca Nicolas Etienne

Miniaturization has been a driving force in many areas of science and technology, most notably in the electronics industry. Droplet-based microfluidics, a methode to produce emulsion drops in a controlled way and at high-throughputs, enables the miniaturiz ...

EPFL2019

Structure and functionality of polyelectrolyte brushes, a surface force perspective

Harm-Anton Klok

The unique functionalities of polyelectrolyte brushes depend on several types of specific interactions, including solvent structure effects, hydrophobic forces, electrostatic interactions, and specific ion interactions. Subtle variations in the solution en ...

2018

Rheological behavior of colloidal suspension with long-range interactions

In this work, we study the constitutive behavior of interacting colloidal suspensions for moderate and high concentrations. Specifically, using a lattice Boltzmann solver, we numerically examine suspensions flowing through narrow channels, and explore the ...

2018

Versatility of Pyridoxal Phosphate as a Coating of Iron Oxide Nanoparticles

Heinrich Hofmann, Josefina Adriana Maria Bastiaansen, Ulrich Aschauer, Marijana Mionic Ebersold, Débora Bonvin

Pyridoxal 5'-phosphate (PLP) is the most important cofactor of vitamin B-6-dependent enzymes, which catalyses a wide range of essential body functions (e.g., metabolism) that could be exploited to specifically target highly metabolic cells, such as tumour ...

Mdpi Ag2017

Biocompatible Amphiphilic Hydrogel–Solid Dimer Particles as Colloidal Surfactants

Esther Amstad

Emulsions of two immiscible liquids can slowly coalesce over time when stabilized by surfactant molecules. Pickering emulsions stabilized by colloidal particles can be much more stable. Here, we fabricate biocompatible amphiphilic dimer particles using a h ...

2017

Viruses at solid-water interfaces: A systematic assessment of interactions driving adsorption

Tamar Kohn, Anne Thérèse Sigstam, Meret Aeppli, Antonius Magdi Hakeem Armanious

Adsorption to solid-water interfaces is a major process governing the fate of waterborne viruses in natural and engineered systems. The relative contributions of different interaction forces to adsorption and their dependence on the physicochemical propert ...

Amer Chemical Soc2016