Publication

Sequential N–O and N–N Bond Cleavage of N-Heterocyclic Carbene-Activated Nitrous Oxide with a Vanadium Complex

Rosario Scopelliti, Kay Severin, Matthew Wodrich, Euro Solari, Alexander Tskhovrebov
2012
Journal Articles

Abstract

Chemically induced bond cleavage of nitrous oxide typically proceeds by rupture of the N–O bond with concomitant O-atom transfer and liberation of dinitrogen. On a few occasions, N–N bond scission has been observed instead. We report a reaction sequence involving an N-heterocyclic carbene and a vanadium complex that results in cleavage of both the N–O bond and the N–N bond.

Official source

https://infoscience.epfl.ch/entities/publication/d4febd77-8829-4002-b6b9-f00c3795baa0

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Sequential N–O and N–N Bond Cleavage of N-Heterocyclic Carbene-Activated Nitrous Oxide with a Vanadium Complex

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