Variant and Invariant States for Reaction Systems

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Vapor compression and energy dissipation in a collapsing laser-induced bubble

Mohamed Farhat, Danail Obreschkow, Davide Bernardo Preso, Armand Baptiste Sieber

The composition of the gaseous phase of cavitation bubbles and its role on the collapse remains to date poorly understood. In this work, experiments of single cavitation bubbles in aqueous ammonia serve as a novel approach to investigate the effect of the ...

Aip Publishing2024

Thermal conductivity of Li 3 PS 4 solid electrolytes with ab initio accuracy

Michele Ceriotti, Federico Grasselli, Davide Tisi, Lorenzo Gigli

The vast amount of computational studies on electrical conduction in solid-state electrolytes is not mirrored by comparable efforts addressing thermal conduction, which has been scarcely investigated despite its relevance to thermal management and (over)he ...

Amer Physical Soc2024

Lewis acid catalyzed [4+2] annulation of bicyclobutanes with dienol ethers for the synthesis of bicyclo[4.1.1]octanes

Jérôme Waser, Stefano Nicolai

Bicyclic carbocycles containing a high fraction of Csp3 have become highly attractive synthetic targets because of the multiple applications they have found in medicinal chemistry. The formal cycloaddition of bicyclobutanes (BCBs) with two- or three-atom p ...

Royal Soc Chemistry2024

A holistic investigation of photocatalytic hydrogen generation

Sangram Ashok Savant

Photocatalytic (PC) solar hydrogen production is a promising way to provide green hydrogen using only sunlight and abundant reactants such as water. PC approaches use catalytically active semiconductor particles suspended in liquid electrolytes. The partic ...

EPFL2023

Design and operational guidelines of solar-driven catalytic conversion of CO2 and H2 to fuels

Sophia Haussener, Sha Li

Sunlight-powered catalytic conversion of CO2 and (green) H2 into fuels and chemicals via Sabatier and reverse water gas shift (RWGS) processes offers a promising solution to reduce greenhouse gas emissions and increase renewable energy utilization. The suc ...

ELSEVIER SCI LTD2023

Metal Catalysts for the Electrochemical Reduction of CO2

Cedric David Koolen

The world by and large has adopted the The Paris Agreement, which commits any signing party to cut greenhouse emissions drastically and prevent global heating above 2 °C beyond pre-industrial levels. For this ambitious goal to be met, ratifying states need ...

EPFL2023

Extension of GeN-Foam to departure from nucleate boiling prediction and validation against the OECD/NRC PSBT benchmark

Carlo Fiorina, Alessandro Scolaro

The prediction of departure from nucleate boiling (DNB) has always been a crucial aspect of thermal-hydraulic codes for the analysis of Light Water Reactors. In this paper, GeN-Foam, a multi-physics code developed based on OpenFOAM, has been enhanced to in ...

Elsevier Science Sa2023

Design of an Instrumented Fuel Rod for Intra-pin Neutron Flux Measurements in the CROCUS Experimental Reactor

Andreas Pautz, Vincent Pierre Lamirand, Mathieu Hursin, Thomas Jean-François Ligonnet, Tom Mager, Won Dong Shin

In response to the need for validating high-fidelity deterministic neutronics solvers capable of pin-resolved neutron flux distributions, an instrumented fuel rod was designed for the experimental reactor CROCUS, operated by EPFL’s Laboratory for Reactor P ...

2023

Down-conversion of a single photon as a probe of many-body localization

Cristiano Ciuti

Decay of a particle into more particles is a ubiquitous phenomenon to interacting quantum systems, taking place in colliders, nuclear reactors or solids. In a nonlinear medium, even a single photon would decay by down-converting (splitting) into lower-freq ...

NATURE PORTFOLIO2023