Publication

Shape and Size-Tailored Pd Nanocrystals to Study the Structure Sensitivity of 2-Methyl-3-butyn-2-ol Hydrogenation: Effect of the Stabilizing Agent

Lioubov Kiwi
2012
Journal Articles

Abstract

Uniform Pd nanocrystals of cubic, octahedral and cube-octahedral shapes were synthesized via a solution-phase method using two stabilizers: poly (vinyl pyrrolidone) (PVP) and di-2-ethylhexylsulfoccinate (AOT) and tested in the hydrogenation of 2-methyl-3-butyn-2-ol. The AOT-stabilized Pd nanocrystals were found to be an order of magnitude more active, but less selective than those stabilized by PVP. This could be attributed to a stronger interaction of PVP with surface Pd by adsorbed N-containing groups. The results obtained were rationalized applying a two-site Langmuir-Hinshelwood kinetic model that allowed predicting 3-4 nm cubic or octahedral nanocrystals stabilized by AOT as the optimum active phase ensuring the highest production rate of target MBE.

Official source

https://infoscience.epfl.ch/entities/publication/cc8345b2-2ef8-468c-80b7-ad6a16872e19

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Lioubov Kiwi
2012
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/cc8345b2-2ef8-468c-80b7-ad6a16872e19

About this result

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