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Supporting data for the publication "Coherent superpositions of three states for phosphorous donors in silicon prepared using THz radiation", describing experimental results from Figures 4-7. The data are in .csv format; columns and units for each file are described in the relevant readme file. The data are given in sufficiently compact states for a reader of the paper to reproduce the figures. Spectral data presented are related to their interferograms by simple Fourier Transform methods. The source interferograms are derived from explicit records of oscilloscope traces, which are verbose and inefficient. Consequently, these raw data files are not included in the dataset. Raw oscilloscope traces will be made available by the authors on request.