Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

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In comparison with Ru-II-arene compounds, the medicinal potential of homologous Ru-II-tpm compounds [tpm = tris(pyrazolyl)methane] is underexplored. Pyridine, 4-pyridinemethanol and four functionalized pyridines, synthesized from the esterification of 4-py ...

The Schiff-bases [N,N'-Bis(2-hydroxybenzylidene)-benzene-1,4-diamine (L-1), N,N'-Bis(5-bromo-2-hydroxybenzylidene)-benzene-1,4-diamine (L-2), N,N'-Bis(2-hydroxy-3-methoxy-benzylidene)-benzene-1,4-diamine (L-3), and N,N'-Bis(2-hydroxynaphthylidene)-benzene- ...

Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis of ...

Decades of uranium-related activities such as ore mining, nuclear power generation, weapon manufacture, storage of nuclear wastes, have contributed to the release of U in the environment. U occurrence is concerning, since in surface environments, U is typi ...

Over the past decade, lead halide perovskites (LHPs) have received considerable attention thanks to their impressive optoelectronic properties. Today, LHP-based devices are one of the most efficient single-junction solar cells, with power-conversion effici ...

A new solid-state method was used to introduce a furan-thiourea polymer into the pores of a MOF, Cr-BDC. Next, the activity of the new MOF-polymer composite containing Pd was assessed in the catalytic hydrodeoxygenation of vanillin, a biomass derived chemi ...

Biosensors are indispensable tools for public, global, and personalized healthcare as they provide tests that can be used from early disease detection and treatment monitoring to preventing pandemics. We introduce single-wavelength imaging biosensors capab ...

Understanding the real aging of Diesel oxidation catalysts (DOC) is key to predict their useful lifetime. This work comprises a detailed study of a commercial DOC in its unused state and after use in vehicle for 288,000 km. The activity of the samples was ...

Light matter interactions such as extinction, reflection, and transmission can be described by classical optics. Dur-ing the past decades, research focused on a novel resonant extinction type called plasmonics that allows for en-hancement of both types of ...

We present a first-principles investigation of the structural, electronic, and magnetic properties of the pristine and Fe-doped alpha-MnO2 using density-functional theory with extended Hubbard functionals. The onsite U and intersite V Hubbard parameters ar ...

Knowledge of the oxidation state of metal centres in compounds and materials helps in the understanding of their chemical bonding and properties. Chemists have developed theories to predict oxidation states based on electron-counting rules, but these can f ...

Amorphous solids are structurally disordered. They are very common and include glasses, colloids, and granular materials, but are far less understood than crystalline solids. Key aspects of these materials are controlled by the presence of excitations in w ...

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

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Anticancer ruthenium(II) tris(pyrazolyl)methane complexes with bioactive co-ligands

Binding affinity of p-PD-based schiff-bases towards human serum albumin; in-vitro and in-silico assessment

Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents

Insights into the microbial reduction of pentavalent and hexavalent uranium species by Shewanella oneidensis MR-1

Ultrafast carrier and quasiparticle dynamics in strongly confined perovskite nanoplatelets

Solid-state synthesis of a MOF/polymer composite for hydrodeoxygenation of vanillin

Imaging-based spectrometer-less optofluidic biosensors based on dielectric metasurfaces for detecting extracellular vesicles

On the relevance of P poisoning in real-world DOC aging

Engineering Absorption for Foil Applications

Pivotal Role of Intersite Hubbard Interactions in Fe-Doped alpha-MnO2

Using collective knowledge to assign oxidation states of metal cations in metal-organic frameworks

Local excitations in amorphous solids