Publication

Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Andrew Douglas Phillips
2007
Journal Articles

Abstract

Formation of a vacant coordination site on a Ru center permits an unusual binding of small molecules such as ethylene, acetylene, and dihydrogen, resulting in the transformation of the chelating β-diketiminate ligand to a β-diimine. These representative species are observed during the catalytic hydrogenation of styrene.

Official source

https://infoscience.epfl.ch/entities/publication/c2d74420-321c-4652-9e35-fd4a3da76307

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Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate

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