Correlation function (statistical mechanics)In statistical mechanics, the correlation function is a measure of the order in a system, as characterized by a mathematical correlation function. Correlation functions describe how microscopic variables, such as spin and density, at different positions are related. More specifically, correlation functions quantify how microscopic variables co-vary with one another on average across space and time. A classic example of such spatial correlations is in ferro- and antiferromagnetic materials, where the spins prefer to align parallel and antiparallel with their nearest neighbors, respectively.
Ideal (ring theory)In mathematics, and more specifically in ring theory, an ideal of a ring is a special subset of its elements. Ideals generalize certain subsets of the integers, such as the even numbers or the multiples of 3. Addition and subtraction of even numbers preserves evenness, and multiplying an even number by any integer (even or odd) results in an even number; these closure and absorption properties are the defining properties of an ideal.
Fractional idealIn mathematics, in particular commutative algebra, the concept of fractional ideal is introduced in the context of integral domains and is particularly fruitful in the study of Dedekind domains. In some sense, fractional ideals of an integral domain are like ideals where denominators are allowed. In contexts where fractional ideals and ordinary ring ideals are both under discussion, the latter are sometimes termed integral ideals for clarity. Let be an integral domain, and let be its field of fractions.
Maximal idealIn mathematics, more specifically in ring theory, a maximal ideal is an ideal that is maximal (with respect to set inclusion) amongst all proper ideals. In other words, I is a maximal ideal of a ring R if there are no other ideals contained between I and R. Maximal ideals are important because the quotients of rings by maximal ideals are simple rings, and in the special case of unital commutative rings they are also fields.
Black hole thermodynamicsIn physics, black hole thermodynamics is the area of study that seeks to reconcile the laws of thermodynamics with the existence of black hole event horizons. As the study of the statistical mechanics of black-body radiation led to the development of the theory of quantum mechanics, the effort to understand the statistical mechanics of black holes has had a deep impact upon the understanding of quantum gravity, leading to the formulation of the holographic principle. The second law of thermodynamics requires that black holes have entropy.
Reaction mechanismIn chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases. The conjectured mechanism is chosen because it is thermodynamically feasible and has experimental support in isolated intermediates (see next section) or other quantitative and qualitative characteristics of the reaction.
Chemical affinityIn chemical physics and physical chemistry, chemical affinity is the electronic property by which dissimilar chemical species are capable of forming chemical compounds. Chemical affinity can also refer to the tendency of an atom or compound to combine by chemical reaction with atoms or compounds of unlike composition. The idea of affinity is extremely old. Many attempts have been made at identifying its origins. The majority of such attempts, however, except in a general manner, end in futility since "affinities" lie at the basis of all magic, thereby pre-dating science.
Lewis acids and basesA Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that has a filled orbital containing an electron pair which is not involved in bonding but may form a dative bond with a Lewis acid to form a Lewis adduct. For example, NH3 is a Lewis base, because it can donate its lone pair of electrons.
Minimal idealIn the branch of abstract algebra known as ring theory, a minimal right ideal of a ring R is a non-zero right ideal which contains no other non-zero right ideal. Likewise, a minimal left ideal is a non-zero left ideal of R containing no other non-zero left ideals of R, and a minimal ideal of R is a non-zero ideal containing no other non-zero two-sided ideal of R . In other words, minimal right ideals are minimal elements of the partially ordered set (poset) of non-zero right ideals of R ordered by inclusion.
Ideal solutionIn chemistry, an ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. The enthalpy of mixing is zero as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes. The vapor pressures of the solvent and solute obey Raoult's law and Henry's law, respectively, and the activity coefficient (which measures deviation from ideality) is equal to one for each component.
Ideal (order theory)In mathematical order theory, an ideal is a special subset of a partially ordered set (poset). Although this term historically was derived from the notion of a ring ideal of abstract algebra, it has subsequently been generalized to a different notion. Ideals are of great importance for many constructions in order and lattice theory. A subset I of a partially ordered set is an ideal, if the following conditions hold: I is non-empty, for every x in I and y in P, y ≤ x implies that y is in I (I is a lower set), for every x, y in I, there is some element z in I, such that x ≤ z and y ≤ z (I is a directed set).
Real numberIn mathematics, a real number is a number that can be used to measure a continuous one-dimensional quantity such as a distance, duration or temperature. Here, continuous means that pairs of values can have arbitrarily small differences. Every real number can be almost uniquely represented by an infinite decimal expansion. The real numbers are fundamental in calculus (and more generally in all mathematics), in particular by their role in the classical definitions of limits, continuity and derivatives.
