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Based on a data sample corresponding to an integrated luminosity of 6.4 fb − 1 of e + e − annihilation and collected with the BESIII detector at 13 center-of-mass energy points ranging between 4.600 GeV and 4.950 GeV, we report the first observation of the singly Cabibbo-suppressed decay with a statistical significance of 5.9 σ . The branching fraction is determined to be . In addition, the decay has also been investigated, and the evidence for this decay is obtained with a statistical significance of 3.7 σ .