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The photosensitized reduction of carbon dioxide by the molecular catalyst [Ru(bpy)2(CO)L] is studied in a biphasic liquid-condensed gas system. Increasing pressure is shown to enhance the initial production rate and turnover number of the catalyst before deactivation of the system, especially for formation of carbon monoxide.
Andreas Züttel, Thi Ha My Pham, Loris Giovanni Lombardo, Zohreh Akbari