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Based on (10087 +/- 44) x 10(6) J/psi events collected with the BESIII detector, we search for the lepton number violating decay J/psi = K+ K+ e(-) e(-) + c.c. for the first time. The upper limit on the branching fraction of this decay is set to at the 90% confidence level with a frequentist method. This is the first search for J/psi decays with a lepton number change by two, offering valuable insights into the underlying physical processes.