Publication

A Spectroscopic and Computational Study of a Photoinduced Cross-Dehydrogenative Coupling Reaction of a Stable Semiquinone Radical

Chenyi Yi, Jakob Grilj
2012
Journal Articles

Abstract

Norrish-type-II reaction on a semiquinone radical: Stable semiquinone radicals serve as novel molecular platforms on which a Norrish-type-II photoreaction can be initiated. A detailed reaction scheme involving a 1,5-hydrogen transfer followed by a cyclization step that finally leads to a new Cï£¿C bond formation could be verified. Transient absorption spectroscopy and DFT calculations trace convincingly the intermediates and transition states along the reaction path (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Official source

https://infoscience.epfl.ch/entities/publication/a9882aa0-24cd-45ed-b1ed-76231a03235e

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A Spectroscopic and Computational Study of a Photoinduced Cross-Dehydrogenative Coupling Reaction of a Stable Semiquinone Radical

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