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When gold nanoparticles are coated with binary mixtures of dislike ligand molecules, separation in the ligand shell occurs; if the particles are smaller than a threshold size the separation is solely enthalpy driven leading to the spontaneous formation of Janus particles.
Sylvie Roke, Arianna Marchioro, Marie Bischoff
Francesco Stellacci, Matteo Gasbarri, Zhi Luo