Publication

Near-infrared→Visible light upconversion in a molecular trinuclear d-f-d complex

Jean-Claude Bünzli
2011
Journal Articles

Abstract

Giving the green light: The connection of two CrIII sensitizers around a central ErIII acceptor in a self-assembled cation provides high local metal concentrations that favor efficient nonlinear energy transfer upconversion luminescence (see picture). Upon selective low-energy near-infrared irradiation of CrIII-centered transitions, 1 displays an unprecedented molecular two-photon upconverted green ErIII-centered emission. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Jean-Claude Bünzli
2011
Journal Articles

Abstract

Official source

Related concepts (9)

Thermal radiation

Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) is converted to electromagnetic radiation. All matter with a temperature greater than absolute zero emits thermal radiation. At room temperature, most of the emission is in the infrared (IR) spectrum. Particle motion results in charge-acceleration or dipole oscillation which produces electromagnetic radiation.

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Passive daytime radiative cooling (PDRC) is a renewable cooling method proposed as a solution to global warming of enhancing terrestrial heat flow to outer space through the installation of thermally-emissive surfaces on Earth that require zero energy consumption or pollution. Because all materials in nature absorb more heat during the day than at night, PDRC surfaces are designed to be high in solar reflectance (to minimize heat gain) and strong in longwave infrared (LWIR) thermal radiation heat transfer through the atmosphere's infrared window (8–13 μm) to cool temperatures during the daytime.

Metal–organic framework

Metal–organic frameworks (MOFs) are a class of compounds consisting of metal clusters (also known as SBUs) coordinated to organic ligands to form one-, two-, or three-dimensional structures. The organic ligands included are sometimes referred to as "struts" or "linkers", one example being 1,4-benzenedicarboxylic acid (BDC). More formally, a metal–organic framework is an organic-inorganic porous extended structure. An extended structure is a structure whose sub-units occur in a constant ratio and are arranged in a repeating pattern.