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We study PBW bases of the untwisted quantum loop group Uq(L𝔤) (in the Drinfeld new presentation) using the combinatorics of loop words, by generalizing the treatment of [29,30,43] in the finite type case. As an application, we prove that Enriquez' homomorphism [11] from the positive half of the quantum loop group to the trigonometric degeneration of Feigin-Odesskii's elliptic algebra [15] associated to 𝔤 is an isomorphism.