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A review on isolated cationic and neutral homoat. heavier group 15 cages and clusters, charged or non-charged assemblies of two or more elemental atoms E (E = P, As, Sb, Bi) without stabilizing (bulky) ligands. It focuses on the recent developments in the condensed as well as the gas phase and only key predating 1985 are given. [on SciFinder (R)]