Publication

Die Stereochemie der fragmentierenden Enthalogenierung von 1-Chlor-1-fluor-2-(1-halogenalkyl)cyclopropanen

Manfred Schlosser
1980
Journal Articles

Abstract

A no. of model substrates, e.g., I (X = Br, iodo) (anti/cis), were submitted to Zn-promoted fragmentation and the compn. of the resulting mixt. of isomeric fluorodienes was detd. The exocyclic reaction center, bearing the electrofugal leaving group, undergoes almost complete stereochem. randomization, while ring opening proceeds stereoselectively. The stereochem. results are related to changes in electron configuration occurring during the reaction. [on SciFinder (R)]

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Manfred Schlosser
1980
Journal Articles

Abstract

Official source

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Die Stereochemie der fragmentierenden Enthalogenierung von 1-Chlor-1-fluor-2-(1-halogenalkyl)cyclopropanen

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