J-couplingIn nuclear chemistry and nuclear physics, J-couplings (also called spin-spin coupling or indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. In NMR spectroscopy, J-coupling contains information about relative bond distances and angles. Most importantly, J-coupling provides information on the connectivity of chemical bonds.
SpectroscopySpectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO).
Two-dimensional nuclear magnetic resonance spectroscopyTwo-dimensional nuclear magnetic resonance spectroscopy (2D NMR) is a set of nuclear magnetic resonance spectroscopy (NMR) methods which give data plotted in a space defined by two frequency axes rather than one. Types of 2D NMR include correlation spectroscopy (COSY), J-spectroscopy, exchange spectroscopy (EXSY), and nuclear Overhauser effect spectroscopy (NOESY). Two-dimensional NMR spectra provide more information about a molecule than one-dimensional NMR spectra and are especially useful in determining the structure of a molecule, particularly for molecules that are too complicated to work with using one-dimensional NMR.
Coupling constantIn physics, a coupling constant or gauge coupling parameter (or, more simply, a coupling), is a number that determines the strength of the force exerted in an interaction. Originally, the coupling constant related the force acting between two static bodies to the "charges" of the bodies (i.e. the electric charge for electrostatic and the mass for Newtonian gravity) divided by the distance squared, , between the bodies; thus: in for Newtonian gravity and in for electrostatic.
Fermi's interactionIn particle physics, Fermi's interaction (also the Fermi theory of beta decay or the Fermi four-fermion interaction) is an explanation of the beta decay, proposed by Enrico Fermi in 1933. The theory posits four fermions directly interacting with one another (at one vertex of the associated Feynman diagram). This interaction explains beta decay of a neutron by direct coupling of a neutron with an electron, a neutrino (later determined to be an antineutrino) and a proton.
Nuclear magnetic resonanceNuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca.
Scalar field theoryIn theoretical physics, scalar field theory can refer to a relativistically invariant classical or quantum theory of scalar fields. A scalar field is invariant under any Lorentz transformation. The only fundamental scalar quantum field that has been observed in nature is the Higgs field. However, scalar quantum fields feature in the effective field theory descriptions of many physical phenomena. An example is the pion, which is actually a pseudoscalar.
Yukawa interactionIn particle physics, Yukawa's interaction or Yukawa coupling, named after Hideki Yukawa, is an interaction between particles according to the Yukawa potential. Specifically, it is a scalar field (or pseudoscalar field) φ and a Dirac field ψ of the type The Yukawa interaction was developed to model the strong force between hadrons. A Yukawa interaction is thus used to describe the nuclear force between nucleons mediated by pions (which are pseudoscalar mesons).
Landau poleIn physics, the Landau pole (or the Moscow zero, or the Landau ghost) is the momentum (or energy) scale at which the coupling constant (interaction strength) of a quantum field theory becomes infinite. Such a possibility was pointed out by the physicist Lev Landau and his colleagues. The fact that couplings depend on the momentum (or length) scale is the central idea behind the renormalization group. Landau poles appear in theories that are not asymptotically free, such as quantum electrodynamics (QED) or φ4 theory—a scalar field with a quartic interaction—such as may describe the Higgs boson.
ConvolutionIn mathematics (in particular, functional analysis), convolution is a mathematical operation on two functions (f and g) that produces a third function () that expresses how the shape of one is modified by the other. The term convolution refers to both the result function and to the process of computing it. It is defined as the integral of the product of the two functions after one is reflected about the y-axis and shifted. The choice of which function is reflected and shifted before the integral does not change the integral result (see commutativity).
Phase transitionIn chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure.
ProlineProline (symbol Pro or P) is an organic acid classed as a proteinogenic amino acid (used in the biosynthesis of proteins), although it does not contain the amino group -NH2 but is rather a secondary amine. The secondary amine nitrogen is in the protonated form (NH2+) under biological conditions, while the carboxyl group is in the deprotonated −COO− form. The "side chain" from the α carbon connects to the nitrogen forming a pyrrolidine loop, classifying it as a aliphatic amino acid.
Uncertainty principleIn quantum mechanics, the uncertainty principle (also known as Heisenberg's uncertainty principle) is any of a variety of mathematical inequalities asserting a fundamental limit to the product of the accuracy of certain related pairs of measurements on a quantum system, such as position, x, and momentum, p. Such paired-variables are known as complementary variables or canonically conjugate variables.
Overlap–add methodIn signal processing, the overlap–add method is an efficient way to evaluate the discrete convolution of a very long signal with a finite impulse response (FIR) filter : where h[m] = 0 for m outside the region [1, M]. This article uses common abstract notations, such as or in which it is understood that the functions should be thought of in their totality, rather than at specific instants (see Convolution#Notation). The concept is to divide the problem into multiple convolutions of h[n] with short segments of : where L is an arbitrary segment length.
Overlap–save methodIn signal processing, overlap–save is the traditional name for an efficient way to evaluate the discrete convolution between a very long signal and a finite impulse response (FIR) filter : where h[m] = 0 for m outside the region [1, M]. This article uses common abstract notations, such as or in which it is understood that the functions should be thought of in their totality, rather than at specific instants (see Convolution#Notation). The concept is to compute short segments of y[n] of an arbitrary length L, and concatenate the segments together.
Vertical deflectionThe vertical deflection (VD) or deflection of the vertical (DoV), also known as deflection of the plumb line and astro-geodetic deflection, is a measure of how far the gravity direction at a given point of interest is rotated by local mass anomalies such as nearby mountains. They are widely used in geodesy, for surveying networks and for geophysical purposes. The vertical deflection are the angular components between the true zenith–nadir curve (plumb line) tangent line and the normal vector to the surface of the reference ellipsoid (chosen to approximate the Earth's sea-level surface).
LongitudeLongitude (ˈlɒndʒᵻtjuːd, ˈlɒŋɡᵻ-) is a geographic coordinate that specifies the east–west position of a point on the surface of the Earth, or another celestial body. It is an angular measurement, usually expressed in degrees and denoted by the Greek letter lambda (λ). Meridians are imaginary semicircular lines running from pole to pole that connect points with the same longitude. The prime meridian defines 0° longitude; by convention the International Reference Meridian for the Earth passes near the Royal Observatory in Greenwich, south-east London on the island of Great Britain.
Convolutional neural networkConvolutional neural network (CNN) is a regularized type of feed-forward neural network that learns feature engineering by itself via filters (or kernel) optimization. Vanishing gradients and exploding gradients, seen during backpropagation in earlier neural networks, are prevented by using regularized weights over fewer connections. For example, for each neuron in the fully-connected layer 10,000 weights would be required for processing an image sized 100 × 100 pixels.
Proteinogenic amino acidProteinogenic amino acids are amino acids that are incorporated biosynthetically into proteins during translation. The word "proteinogenic" means "protein creating". Throughout known life, there are 22 genetically encoded (proteinogenic) amino acids, 20 in the standard genetic code and an additional 2 (selenocysteine and pyrrolysine) that can be incorporated by special translation mechanisms.
Amino acidAmino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although over 500 amino acids exist in nature, by far the most important are the α-amino acids, from which proteins are composed. Only 22 α-amino acids appear in the genetic code of all life. Amino acids can be classified according to the locations of the core structural functional groups, as alpha- (α-), beta- (β-), gamma- (γ-) or delta- (δ-) amino acids; other categories relate to polarity, ionization, and side chain group type (aliphatic, acyclic, aromatic, containing hydroxyl or sulfur, etc.
