Publication

Chiral Cationic (CpRu)-Ru-x(II) Complexes for Enantioselective Yne-Enone Cyclizations

Nicolai Cramer, David Kossler
2015
Journal Articles

Abstract

The cydopentadienyl (Cp) group is a ligand of great importance for many transition-metal complexes used in catalysis. Cationic CpRuII complexes with three free coordination sites are highly versatile catalysts for many atom-economic transformations. We report the synthesis of a family of (CpRuII)-Ru-x complexes with chiral Cp ligands keeping the maximum number of available coordination sites. The cationic members are efficient and selective catalysts for yne-enone cyclizations via formal hetero-Diels-Alder reactions. The transformation proceeds in

Official source

https://infoscience.epfl.ch/entities/publication/9529fc90-ca0d-40e1-a6d8-66a376328eae

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Chiral Cationic (CpRu)-Ru-x(II) Complexes for Enantioselective Yne-Enone Cyclizations

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