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A dimensionally stable anode with enhanced durability for use in electrochem. processes (e.g. those involving evolution of Cl2 or O2) is described. The anode consists of a substrate of >=1 metals or metal oxides provided with an outer Ta surface coated with an electrocatalytic IrO2 coating. It has a std. lifetime >14 h-m2/g (preferably >25 h-m2/g). The substrate can be Ti, Ti alloy, Ta or stainless steel 316 and the coating may consist of Ta2O5 and IrO2. [on SciFinder (R)]
Jan Van Herle, Aïcha Hessler-Wyser, Antonin Faes
Introduction
Fundamentals of Thermodynamics
Thermodynamics of Electrochemical Reactions
Example 1
Example 2
Example 3
Nernst Equation
Example 3
Cathodic Reactions in Corrosion
Pourbaix Diagrams
Pourbaix Diagram for Water
Pourbaix Diagram for Metals
Example: Pourbaix Diagram for Fe
Comments on Pourbaix Diagrams
Thermodynamics of High Temperature Corrosion