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Understanding the complexity of quantum states and circuits is a central challenge in quantum information science, with broad implications in many-body physics, high-energy physics and quantum learning theory. A common way to model the behaviour of typical states and circuits involves sampling unitary transformations from the Haar measure on the unitary group. In this work, we depart from this standard approach and instead study structured unitaries drawn from other compact connected groups, namely the symplectic and special orthogonal groups. By leveraging the concentration of measure phenomenon, we establish two main results. We show that random quantum states generated using symplectic or orthogonal unitaries typically exhibit an exponentially large strong state complexity, and are nearly orthogonal to one another. Similar behavior is observed for designs over these groups. Additionally, we demonstrate the average-case hardness of learning circuits composed of gates drawn from such classical groups of unitaries. Taken together, our results demonstrate that structured subgroups can exhibit a complexity comparable to that of the full unitary group.