Publication

Water-soluble analogs of [RuCl3(NO)(PPh3)(2)] and their catalytic activity in the hydrogenation of carbon dioxide and bicarbonate in aqueous solution

Gabor Laurenczy
2003
Journal Articles

Abstract

The new water-soluble ruthenium-nitrosyl complexes [RuCl3(NO)(TPPMS)(2)] and [RuCl3(NO)(TPPTS)(2)] were synthetized and characterized by IR, H-1 and P-31 NMR spectroscopies. The NO stretching frequencies, nu(NO) = 1870 cm(-1) (TPPMS) and 1883 cm(-1) (TPPTS) suggest a linear Ru-N-O arrangements. Reactions with OH- yield the corresponding [RuCl3 (NO2)(P)(2)] derivatives, furthermore, [RuH(NO)(P)(3)] is formed with TPPMS or TPPTS, respectively, under 100 bar H-2 pressure. The new complexes are suitable precatalysts for the hydrogenation of carbon dioxide and/or bicarbonate in aqueous solutions up to a turnover frequency of 400 h(-1) under relatively mild conditions (30 bar H-2, 70 degreesC). (C) 2003 Elsevier Science B.V. All rights reserved.

Official source

https://infoscience.epfl.ch/entities/publication/8e877467-ed7e-4fe0-9edd-59a129ddd179

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Gabor Laurenczy
2003
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/8e877467-ed7e-4fe0-9edd-59a129ddd179

About this result

Related concepts (32)

Aqueous solution

An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word aqueous (which comes from aqua) means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry.

Ammonia solution

Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with the composition [NH4+][OH-], it is actually impossible to isolate samples of NH4OH. The ions NH4+ and OH− do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions.

Solution (chemistry)

In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution.

Related publications (22)

Water-soluble analogs of [RuCl3(NO)(PPh3)(2)] and their catalytic activity in the hydrogenation of carbon dioxide and bicarbonate in aqueous solution

Chat with Graph Search

Recent progress in high-field liquid-state Overhauser dynamic nuclear polarization

Spatial and Temporal Patterns of Alkalinity in an Alpine Headwater Stream Network: Linking Catchment Heterogeneity to Carbon Dynamics

Ligand Exchange-based Synthesis of Azide-functionalized Cu Nanospheres as a Platform for Mn Complex Immobilization and Electrochemical Co2 Reduction