Publication

Cu2OSeO3 turns trigonal with structural transformation and implications for skyrmions

2025

Abstract

The formation and characteristics of magnetic skyrmions are strongly governed by the symmetry of the underlying crystal structure. In this study, we report the discovery of a new trigonal polymorph of Cu2OSeO3, observed exclusively in nanoparticles. Electron diffraction and density functional theory calculations confirm its R3m space group, sharing C3v symmetry with Néel-type skyrmion hosts. This polymorph is likely stabilized by surface effects, suggesting that size-induced structural changes may drive a transformation from Bloch-type to Néel-type skyrmions in Cu2OSeO3. This hypothesis could be consistent with prior unexplained observations of Néel-type skyrmions at the surfaces of bulk crystals, which may result from surface-specific structural distortions. Overall, these findings provide insights into the interplay between size, structure, and magnetism, opening pathways for controlling skyrmionic properties in nanoscale systems.

Official source

https://infoscience.epfl.ch/entities/publication/8bc281e4-2526-4d9e-9401-5623f404b722

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2025

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/8bc281e4-2526-4d9e-9401-5623f404b722

About this result

Related concepts (32)

Precession electron diffraction

Precession electron diffraction (PED) is a specialized method to collect electron diffraction patterns in a transmission electron microscope (TEM). By rotating (precessing) a tilted incident electron beam around the central axis of the microscope, a PED pattern is formed by integration over a collection of diffraction conditions. This produces a quasi-kinematical diffraction pattern that is more suitable as input into direct methods algorithms to determine the crystal structure of the sample.

Skyrmion

In particle theory, the skyrmion (ˈskɜrmi.ɒn) is a topologically stable field configuration of a certain class of non-linear sigma models. It was originally proposed as a model of the nucleon by (and named after) Tony Skyrme in 1961. As a topological soliton in the pion field, it has the remarkable property of being able to model, with reasonable accuracy, multiple low-energy properties of the nucleon, simply by fixing the nucleon radius. It has since found application in solid-state physics, as well as having ties to certain areas of string theory.

Electron diffraction

Electron diffraction refers to changes in the direction of electron beams due to interactions with atoms. Close to the atoms the changes are described as Fresnel diffraction; far away they are called Fraunhofer diffraction. The resulting map of the directions of the electrons far from the sample (Fraunhofer diffraction) is called a diffraction pattern, see for instance Figure 1. These patterns are similar to x-ray and neutron diffraction patterns, and are used to study the atomic structure of gases, liquids, surfaces and bulk solids.

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Cu2OSeO3 turns trigonal with structural transformation and implications for skyrmions

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