This paper presents a preliminary study of the characterization of the surface energy properties of clinker phases (C3S and C3A), kaolin and metakaolin by Inverse Gas Chromatography (IGC). For this, a reliable measurement methodology was developed. By look ...
A wide range of systems were exposed to a seawater-like chloride concentration (0.5 M Cl−) for bulk diffusion experiments over 0.5, 1 and 4 years. Combined with previously published findings on chloride binding and mini-migration testing, the results showe ...
It has long been known that alkalis favor an increase in the early strength of cementitious materials but have a negative impact on long-term strengths. The reasons for the negative effect on later strengths are not clear. In this paper we investigated the ...
Autogenous shrinkage is the unrestrained volume change of cementitious materials occurring at con-stant temperature without any change in mass. It occurs as a consequence of self-desiccation (de-crease of internal relative humidity) and increasing capillar ...
A preliminary assessment of conditions for the industrial manufacture of a new cementitious system based on clinker-calcined clay and limestone, developed by the authors, referred as "low carbon cement" is presented. The new cement enables the substitution ...
The modeling platform µic has been extended to study the hydration of cement based systems. It is shown that the hydration kinetics of alite can be described through the implementation of two mechanisms: a solution controlled dissolution (SCD) mechanism fo ...