Publication

Theoretical Aspects Associated with Charge-transfer Kinetics across Interfaces between Two Immiscible Electrolyte Solutions

Hubert Girault
2007

Abstract

The sections in this article are

Introduction and Scope
Heterogeneous Electron Transfer across ITIES
    Thermodynamic Aspects in Connection to Heterogeneous ET
    Electron-transfer Kinetics
        The Phenomenological Butler–Volmer Expression
        The Rate Constant of Electron Transfer
        The Solvent Reorganization Energy
        Potential Dependence of the Heterogeneous Electron-transfer Rate Constant
    Selected Experimental Results
Ion-transfer Reactions
    Kinetics of Ion-transfer Reactions Based on the Assumption of an Activated Ion-transfer Event
    Interfacial Reaction Independent of the Local Electric Field
    Interfacial Reaction Dependent on the Electric Field
    Kinetics of Ion-transfer Reactions Based on a Transport Description
    General Treatment of Ion-transfer Reactions at ITIES
    The Marcus Model for Ion Transfer at Liquid|Liquid Interfaces
    Other Models
Conclusion and Outlook

Official source

https://infoscience.epfl.ch/entities/publication/81667f63-981d-4c1e-abf7-8777464ce1d0

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Hubert Girault
2007

Abstract

The sections in this article are

Introduction and Scope
Heterogeneous Electron Transfer across ITIES
    Thermodynamic Aspects in Connection to Heterogeneous ET
    Electron-transfer Kinetics
        The Phenomenological Butler–Volmer Expression
        The Rate Constant of Electron Transfer
        The Solvent Reorganization Energy
        Potential Dependence of the Heterogeneous Electron-transfer Rate Constant
    Selected Experimental Results
Ion-transfer Reactions
    Kinetics of Ion-transfer Reactions Based on the Assumption of an Activated Ion-transfer Event
    Interfacial Reaction Independent of the Local Electric Field
    Interfacial Reaction Dependent on the Electric Field
    Kinetics of Ion-transfer Reactions Based on a Transport Description
    General Treatment of Ion-transfer Reactions at ITIES
    The Marcus Model for Ion Transfer at Liquid|Liquid Interfaces
    Other Models
Conclusion and Outlook

Official source

https://infoscience.epfl.ch/entities/publication/81667f63-981d-4c1e-abf7-8777464ce1d0

About this result

Related concepts (32)

Electron transfer

Electron transfer (ET) occurs when an electron relocates from an atom or molecule to another such chemical entity. ET is a mechanistic description of certain kinds of redox reactions involving transfer of electrons. Electrochemical processes are ET reactions. ET reactions are relevant to photosynthesis and respiration and commonly involve transition metal complexes. In organic chemistry ET is a step in some commercial polymerization reactions. It is foundational to photoredox catalysis.

Electrochemical kinetics

Electrochemical kinetics is the field of electrochemistry that studies the rate of electrochemical processes. This includes the study of how process conditions, such as concentration and electric potential, influence the rate of oxidation and reduction (redox) reactions that occur at the surface of an electrode, as well as an investigation into electrochemical reaction mechanisms.

Double layer (surface science)

In surface science, a double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object. The first layer, the surface charge (either positive or negative), consists of ions which are adsorbed onto the object due to chemical interactions.

Related publications (14)

Theoretical Aspects Associated with Charge-transfer Kinetics across Interfaces between Two Immiscible Electrolyte Solutions

Chat with Graph Search

Nanoengineering and Fundamental Insights into Solid-Liquid Interfaces toward Sustainable Energy Applications

Automated Reaction Exploration of Ozonation Processes for Model Olefins in Water

Water Transport Management in a Bipolar Membrane for CO2 Electrolysis Application