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Cross polarization from protons to quadrupolar Li-6 nuclei is combined with dynamic nuclear polarization of protons at 1.2 K and 6.7 T using TEMPOL as a polarizing agent followed by rapid dissolution. Compared to direct Li-6 DNP without cross-polarization, a higher nuclear spin polarization P(Li-6) can be obtained in a shorter time. A double resonance H-1-Li-6 probe was designed that is equipped for Longitudinally Detected Electron Spin Resonance.
Basil Duval, Timothy Goodman, Olivier Sauter, Stefano Coda, Laurie Porte, Benoît Labit, Federico Alberto Alfredo Felici, Antoine Pierre Emmanuel Alexis Merle, Umar Sheikh, Mengdi Kong, Simon Van Mulders, Cristian Sommariva, Alessandro Pau