Publication

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Rosario Scopelliti, Marinella Mazzanti, Farzaneh Fadaei Tirani, Wendy Lee Queen, Anne-Sophie Chauvin, Till Marian Schertenleib, Aurélien René Willauer, Andrei Andreichenko
2023
Journal Articles

Abstract

Rigidtritopic linkers of different sizes were used to buildporous U-(IV) and Th-(IV) 3D frameworks. The charge of the polymerscould be tuned by reaction conditions such as the temperature, pH,solvent, ligand, or metal precursor, yielding a series of neutralor positively or negatively charged frameworks. Postsynthetic solventsubstitution revealed a rare crystal-to-crystal transformation froma cationic to a neutral framework.

Official source

https://infoscience.epfl.ch/entities/publication/7a6aeee1-4610-4b7f-b35e-45511ba4d315

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Chat with Graph Search

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Real- and Q-space travelling: multi-dimensional distribution maps of crystal-lattice strain (epsilon(044)) and tilt of suspended monolithic silicon nanowire structures

α-Diimines as Versatile, Derivatizable Ligands in Ruthenium(II) p-Cymene Anticancer Complexes