Publications related to Uranium redox transition pathways in acetate-amended sediments

Related publications (32)

Atomic level insight into irradiation effects in nuclear fuel materials

Microstructural evolution during in-pile irradiation, radiation damage effects and fission products behavior in UO2 nuclear fuel are key issues in understanding and for the modeling of the performance as well as safety characteristics of nuclear fuels in t ...

EPFL2024

Arctic's hidden hydrocarbon degradation microbes: investigating the effects of hydrocarbon contamination, biostimulation, and a surface washing agent on microbial communities and hydrocarbon biodegradation pathways in high-Arctic beaches

Ianina Altshuler

Background: Canadian Arctic summer sea ice has dramatically declined due to global warming, resulting in the rapid opening of the Northwest Passage (NWP), slated to be a major shipping route connecting the Atlantic and Pacific Oceans by 2040. This developm ...

2024

Fossil biocalcite remains open to isotopic exchange with seawater for tens of millions of years

Anders Meibom, Stéphane Laurent Escrig, Jaroslaw Hubert Stolarski, Cristina Martin Olmos, Arthur Adams, Deyanira Graciela Cisneros Lazaro, Sylvain Louis Bernard

Fossilized remains of marine calcifiers constitute the physical basis for reconstructions of both deep ocean and sea-surface temperatures going back millions of years, but paleoclimate records derived from their isotope and trace-element chemistry can be b ...

Springer Nature2024

Diagenetic isotope exchange in biocalcites for paleoclimate reconstruction

Deyanira Graciela Cisneros Lazaro

The oxygen isotope compositions of fossil biocalcites, such as foraminifera, bivalves, brachiopods, and belemnites have allowed for reconstructions of sea surface and deep ocean temperatures throughout the Phanerozoic and constitute the most important reco ...

EPFL2024

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Megan Renee Keener, Dieuwertje Katelijn Modder, Keerthi Shivaraam Rangaraj Ananthakumar

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Wiley-VCH Verlag GmbH2023

Ultrasonic sediment flux profiling with ACVP Technology: application to sediment-laden Boundary Layer flows

Giovanni De Cesare, David Hurther

Sediment transport in geophysical boundary layer flows has relevance to a broad spectrum of sciences ranging from the physical and chemical, to the biological, ecological and geological. Advances in sediment transport modelling and prediction strongly suff ...

2023

Characterization of Thruster-Induced Turbulence for Fine Sediment Suspension

Giovanni De Cesare, Azin Amini, Montana Marshall

Reservoir sedimentation is a key challenge for storage sustainability because it causes volume loss, affecting hydropower production capacity, dam safety, and flood management. A preliminary EPFL study proposed and studied an innovative device (called SEDM ...

2023

Iron Reduction in Profundal Sediments of Ultraoligotrophic Lake Tahoe under Oxygen-Limited Conditions

Meret Aeppli

Increased periods of bottom water anoxia in deep temperate lakes due to decreasing frequency and depth of water column mixing in a warming climate may result in the reductive dissolution of iron minerals and increased flux of nutrients from the sediment in ...

2023

Experimental modeling of fine sediment routing: SEDMIX device with thrusters

Giovanni De Cesare, Azin Amini, Montana Marshall

Reservoir sedimentation is a key challenge for storage sustainability because it causes volume loss, affecting hydropower production capacity, dam safety, and flood management. A preliminary EPFL study proposed and studied an innovative device (called SEDM ...

CRC Press/Balkema2023

Experimental characterization of root-reinforced riparian sediment deposits in a restored and widened river course

Giovanni De Cesare, Paolo Perona

The Arbogne River is located mainly in the Swiss canton of Fribourg. The River was meandering through the plane at a very low gradient and several exceptional historic floods with large sediment accumulation are mentioned. After important river training wo ...

2023

Clogging of riverbed substrates by fine sediment

Romain Maxime Dubuis

Riverbeds represent the habitat of numerous aquatic species. Exchanges between the groundwater, the hyporheic zone and the surface flow are also essential for river ecosystems. Fine sediment transported by rivers deposits inside or on top of the bed and mo ...

EPFL2023

The clogging of riverbeds: A review of the physical processes

Giovanni De Cesare, Romain Maxime Dubuis

Fine sediment represents an important part of the solid flux of rivers. Due to the size of these particles, they are often transported as suspended load. They gradually fill the pores of the substrate forming the hyporheic zone or cover the substrate by se ...

2023

Influence of the shear stress on fine sediment exchanges with the substrate using UVP measurements

Giovanni De Cesare, Romain Maxime Dubuis

The dynamic of fine sediment in rivers is closely related to the interactions between fine particles, the riverbed and the flow conditions. The accumulation of fine sediment in the riverbed reduces vertical water exchanges and can have detrimental effects ...

2023

Reduction of riverbed clogging related to sediment flushing

Giovanni De Cesare, Romain Maxime Dubuis

The ecological effects of dams on sediment and river flow have been subject to an increasing attention, leading to the implementation of mitigation measures such as environmental flow release and sediment replenishment. However, fine sediment dynamics have ...

CRC Press/Balkema2023

Hydromorphological assessment of sediment augmentation measures in gravel-bed rivers

Christian Mörtl

In the riverine environment, the riverscape, sediment and flow regime are essential drivers for natural habitat dynamics. Today, most water courses in Europe are regulated, and their natural dynamics are impaired. Flood releases coupled with the artificial ...

EPFL2023

Biostimulation as a sustainable solution for acid neutralization and uranium immobilization post acidic in-situ recovery

Rizlan Bernier-Latmani, Pierre Rossi, Thomas Coral

Major uranium (U) deposits worldwide are exploited by acid leaching, known as 'in-situ recovery' (ISR). ISR involves the injection of an acid fluid into ore-bearing aquifers and the pumping of the resulting metal-containing solution through cation exchange ...

2022

Engineering extracellular electron transfer for enhanced energy harvesting in microbial electrochemical devices

Mohammed Mouhib

Microorganisms known as exoelectrogens evolved the ability of transporting electrons across insulating biological membranes. In a physiological context, this enables respiration on extracellular electron acceptors and electron transfer to other organisms. ...

EPFL2023

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Marinella Mazzanti

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

SWISS CHEMICAL SOC2022

Limits between surface and inner clogging of riverbed by fine sediment

Giovanni De Cesare, Romain Maxime Dubuis, Romain Dubuis

The deposition of fine sediment on top of the riverbed affects the reproduction of spawning fishes and some species of benthos. The clogging of the substrate resulting from this deposition is a well-known issue in rivers affected by anthropogenic activity ...

2023