Publication

Mixed ruthenium catalyst for methanation of hydrogen and carbon dioxide

Michael Graetzel, Juan Kiwi, Ravindranathan Thampi
1989
Patents

Abstract

A catalyst having a mixture of Ru and RuOx, wherein x is greater than 0 and equal to or less than 2, supported by a suitable metal oxide support material is suitable for the heterogeneous catalytic gas phase direct methane production from hydrogen and carbon dioxide at mild temperatures as low as 25 DEG C. and atmospheric pressure. Photo-methanation using such catalysts having photoexcitable support materials significantly increases the rate of methane production and the methane yield, yielding almost stoichiometrically quantitative amounts of methane according to the Sabatier reaction.

Official source

https://infoscience.epfl.ch/entities/publication/75d23a1a-ab81-41ee-8772-7dd1f214b072

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Michael Graetzel, Juan Kiwi, Ravindranathan Thampi
1989
Patents

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/75d23a1a-ab81-41ee-8772-7dd1f214b072

About this result

Related concepts (32)

Methane

Methane (USˈmɛθeɪn , UKˈmiːθeɪn ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes.

Methane emissions

Increasing methane emissions are a major contributor to the rising concentration of greenhouse gases in Earth's atmosphere, and are responsible for up to one-third of near-term global heating. During 2019, about 60% (360 million tons) of methane released globally was from human activities, while natural sources contributed about 40% (230 million tons). Reducing methane emissions by capturing and utilizing the gas can produce simultaneous environmental and economic benefits.

Methane clathrate

Methane clathrate (CH4·5.75H2O) or (8CH4·46H2O), also called methane hydrate, hydromethane, methane ice, fire ice, natural gas hydrate, or gas hydrate, is a solid clathrate compound (more specifically, a clathrate hydrate) in which a large amount of methane is trapped within a crystal structure of water, forming a solid similar to ice. Originally thought to occur only in the outer regions of the Solar System, where temperatures are low and water ice is common, significant deposits of methane clathrate have been found under sediments on the ocean floors of the Earth.

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Mixed ruthenium catalyst for methanation of hydrogen and carbon dioxide

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