Publication

Rezepte und Zutaten für kontrollierte CC-Verknüpfungen mit Organometall-Reagentien

Manfred Schlosser
1974
Journal Articles

Abstract

A review with 37 refs. about C-C linkages with organometallic compds., esp. the Cu-catalyzed alkylation of Grignard reagents, giving satd. and unsatd. hydrocarbons optionally substituted by functional groups, and regio- and stereoselective olefin synthesis with allylpotassium compds. [on SciFinder (R)]

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Manfred Schlosser
1974
Journal Articles

Abstract

Official source

Related concepts (19)

Grignard reagent

A Grignard reagent or Grignard compound is a chemical compound with the general formula , where X is a halogen and R is an organic group, normally an alkyl or aryl. Two typical examples are methylmagnesium chloride and phenylmagnesium bromide . They are a subclass of the organomagnesium compounds. Grignard compounds are popular reagents in organic synthesis for creating new carbon-carbon bonds. For example, when reacted with another halogenated compound in the presence of a suitable catalyst, they typically yield and the magnesium halide as a byproduct; and the latter is insoluble in the solvents normally used.

Functional group

In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest of the molecule's composition. This enables systematic prediction of chemical reactions and behavior of chemical compounds and the design of chemical synthesis. The reactivity of a functional group can be modified by other functional groups nearby.

Organolithium reagent

In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds. These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. Organolithium reagents are used in industry as an initiator for anionic polymerization, which leads to the production of various elastomers.

Related publications (1)

Rezepte und Zutaten für kontrollierte CC-Verknüpfungen mit Organometall-Reagentien

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Prescriptions and Ingredients for Controlled CC Bond Formation