Transition-Metal-Containing Bifunctional Catalysts: Design and Catalytic Applications

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The development of novel materials capable of securely storing hydrogen at high volumetric and gravimetric densities is a requirement for the wide-scale usage of hydrogen as an energy carrier. In recent years, great efforts via nanoscale tuning and designi ...

The need for efficient and selective catalysts, capable of driving important conversions to build a more sustainable society, encourages the development of synthetic approaches towards new nanomaterials. Cu-based bimetallic nanoparticles (NPs) promise to f ...

The design of novel cathode materials for Li-ion batteries would greatly benefit from accurate first-principles predictions of structural, electronic, and magnetic properties as well as intercalation voltages in compounds containing transition-metal elemen ...

Transition metal hexacyanometallates, so-called Prussian Blue Analogs (PBAs), have received massive attention as aqueous Na-ion battery electrode materials for large-scale energy storage systems not only due to their simple and low-cost synthesis procedure ...

Direct borohydride fuel cells (DBFCs) operate with liquid H2O2 and a high-energy-density NaBH4 solution. A facile, direct synthesis method using a non-noble nickel catalyst for the DBFC anode is shown. The complex anode reaction with an anion-exchange iono ...

Among all CO2 electroreduction products, methane (CH4) and ethylene (C2H4) are two typical and valuable hydrocarbon products which are formed in two different pathways: hydrogenation and dimerization reactions of the same CO intermediate. Theoretical studi ...

New ternary and higher order inorganic materials are needed for a large variety of applications, yet their synthesis still represents a chemistry challenge. Herein, we focus on the synthesis of Cu-M-S nanocrystals (where M = V, Cr, Mn) via a wet-chemistry ...

The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...

Combining a catalytic enantioselective reaction with dimerization in a single operation is an efficient way to upgrade the enantiomeric excesses (ee) of the product. Palladium-catalyzed reaction of N-(2-iodophenyl)-N-methyl methacrylamide derivatives with ...

In the last two decades, Magnetic Resonance Imaging (MRI) has evolved into one of the most powerful techniques in diagnostic clinical medicine and biomedical research. MRI is primarily used to produce anatomical images, but may also give information on the ...

Transition-Metal-Containing Bifunctional Catalysts: Design and Catalytic Applications

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Nanoscale engineering of solid-state materials for boosting hydrogen storage

Galvanic replacement reactions of Ga and In with Cu for the synthesis of bimetallic nanoparticles

Accurate Electronic Properties and Intercalation Voltages of Olivine-Type Li-Ion Cathode Materials from Extended Hubbard Functionals

High voltage and superior cyclability of indium hexacyanoferrate cathodes for aqueous Na-ion batteries enabled by superconcentrated NaClO4 electrolytes

Selective Borohydride Oxidation Reaction on Nickel Catalyst with Anion and Cation Exchange Ionomer for High-Performance Direct Borohydride Fuel Cells

Controllable CO adsorption determines ethylene and methane productions from CO2 electroreduction

Colloidal Synthesis of Cu-M-S (M = V, Cr, Mn) Nanocrystals by Tuning the Copper Precursor Reactivity

Mechanistic implications of lanthanum-modification on gold-catalyzed formic acid decomposition under SCR-relevant conditions

Catalytic Enantioselective Double Carbopalladation/C−H Functionalization with Statistical Amplification of Product Enantiopurity: A Convertible Linker Approach

Novel chelators for MRI applications : stability and relaxation properties of their metal complexes