Publication

Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Gabor Laurenczy
2002
Journal Articles

Abstract

In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation (eta(6)-C6H6) (eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2) 2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.

Official source

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Mechanistic in situ high-pressure NMR studies of benzene hydrogenation by supramolecular cluster catalysis with [(eta(6)-C6H6)(eta(6)-C6Me6)(2)Ru-3(mu(3)-O)(mu(2)-OH)(mu(2)-H)(2)][BF4]

Chat with Graph Search

Stereochemical effects in supramolecular self-assembly at surfaces: 1-D versus 2-D enantiomorphic ordering for PVBA and PEBA on Ag(111)

A Synthetic Peptide Ligase. Mechanistic Investigations