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Frustrated Lewis pairs (FLP) which rely on the cooperative action of Lewis acids and Lewis bases, played a prominent role in the advancement of main-group catalysis. While the early days of FLP chemistry witnessed the dominance of boranes, there is a growing body of reports on alternative Lewis acids derived from groups 14 and 15. This short review focuses on the discovery of such non-boron candidates reported since 2015.
Anne-Clémence Corminboeuf, Rubén Laplaza Solanas, Shubhajit Das
Kumar Varoon Agrawal, Mostapha Dakhchoune, Xuekui Duan