Transformation of a Chiral Nanoporous Bimetallic Cyano-Bridged Framework Triggered by Dehydration/Rehydration

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Comprehensive study of carbon dioxide adsorption in the metal-organic frameworks M-2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn)

Berend Smit, Wendy Lee Queen

Analysis of the CO2 adsorption properties of a well-known series of metal-organic frameworks M-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate; M = Mg, Mn, Fe, Co, Ni, Cu, and Zn) is carried out in tandem with in situ structural studies to ident ...

Royal Soc Chemistry2014

Biporous Metal-Organic Framework with Tunable CO2/CH4 Separation Performance Facilitated by Intrinsic Flexibility

Berend Smit, Kyriakos Stylianou, Seyedmohamad Moosavi, Daniele Ongari, Andrzej Gladysiak, Arunraj Chidambaram, Peter George Boyd, Kathryn Suzanne Deeg

In this work, we report the synthesis of SION-8, a novel metal-organic framework (MOF) based on Ca(II) and a tetracarboxylate ligand TBAPy(4-) endowed with two chemically distinct types of pores characterized by their hydrophobic and hydrophilic properties ...

2018

Design of Surface-Supported Bio-inspired Networks for CO2 and O2 Activation at Room Temperature

Daniel Eduardo Hurtado Salinas

The structure of a biological system defines its function. Therefore, nature has developed sophisticated systems that catalyze chemical reactions that are vital for life on earth. For instance, the photosynthesis is a biological process that is partially r ...

EPFL2018

Rational Design of a Low-Cost, High-Performance Metal-Organic Framework for Hydrogen Storage and Carbon Capture

Berend Smit, Kyriakos Stylianou, Andrzej Gladysiak

We present the in silico design of a MOF-74 analogue, hereon known as M-2(DHFUMA) [M = Mg, Fe, Co, Ni, Zn], with enhanced small-molecule adsorption properties over the original M-2(DOBDC) series. Constructed from 2,3-dihydroxyfumarate (DHFUMA), an aliphati ...

2017

Structural characterization of framework-gas interactions in the metal-organic framework Co-2(dobdc) by in situ single-crystal X-ray diffraction

Wendy Lee Queen

The crystallographic characterization of framework-guest interactions in metal-organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with ...

2017

Hydrogen Storage in the Expanded Pore Metal-Organic Frameworks M-2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn)

Wendy Lee Queen

The hydrogen storage properties of a new family of isostructural metal organic frameworks are reported. The frameworks M-2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn; dobpdc(4-) = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) are analogous to the widely studied M-2(do ...

Amer Chemical Soc2016

Single crystals of superconducting SmFeAsOHx: Structure and properties

László Forró, Alla Arakcheeva, Richard Gaal, Sergiy Katrych, Andrea Pisoni, Ping Huang, Péter Krisztián Matus

We report the synthesis, structure, and superconducting properties of single crystals of SmFeAsOHx. The crystals were grown at high pressure and high temperature using a cubic anvil technique. H-1-NMR studies confirm the presence of H atoms in the samples. ...

Amer Physical Soc2016