Publication

Unsymmetrical extended pi-conjugated zinc phthalocyanine for sensitization of nanocrystalline TiO2 films

Michael Graetzel, Mohammad Khaja Nazeeruddin, Jun Ho Yum
2009
Journal Articles

Abstract

We have designed and synthesized a new unsymmetrical zinc phthalocyanine based on 'push-pull' and extended pi-conjugation concept, PCH008. The new sensitizer was fully characterized by CHN anlysis, UV-Vis., fluorescence spectroscopies and cyclic voltammetry. The new sensitizer which upon anchoring onto nanocrystalline TiO2 film exhibit a short circuit current of 5.63 mA cm(-2), open circuit potential of 557.0 mV and a fill factor of 0.75 corresponding to an overall conversion efficiency of 2.35% under standard global air mass (AM) 1.5 solar conditions and compared its performance with literature reported phthalocyanine dyes.

Official source

https://infoscience.epfl.ch/entities/publication/6b16e402-4b1a-4c39-b428-7983e285808e

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Michael Graetzel, Mohammad Khaja Nazeeruddin, Jun Ho Yum
2009
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/6b16e402-4b1a-4c39-b428-7983e285808e

About this result

Related concepts (27)

Solar-cell efficiency

Solar-cell efficiency refers to the portion of energy in the form of sunlight that can be converted via photovoltaics into electricity by the solar cell. The efficiency of the solar cells used in a photovoltaic system, in combination with latitude and climate, determines the annual energy output of the system. For example, a solar panel with 20% efficiency and an area of 1 m2 will produce 200 kWh/yr at Standard Test Conditions if exposed to the Standard Test Condition solar irradiance value of 1000 W/m2 for 2.

Nanocrystal solar cell

Nanocrystal solar cells are solar cells based on a substrate with a coating of nanocrystals. The nanocrystals are typically based on silicon, CdTe or CIGS and the substrates are generally silicon or various organic conductors. Quantum dot solar cells are a variant of this approach which take advantage of quantum mechanical effects to extract further performance. Dye-sensitized solar cells are another related approach, but in this case the nano-structuring is a part of the substrate.

Short circuit

A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circuit. The opposite of a short circuit is an open circuit, which is an infinite resistance (or very high impedance) between two nodes. A short circuit is an abnormal connection between two nodes of an electric circuit intended to be at different voltages.

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