Publications related to Iridium-Catalyzed Acid-Assisted Hydrogenation of Oximes to Hydroxylamines

Related publications (15)

CO2-mediated hydrogen storage and release cycles realized by a bimetallic ruthenium complex in pure water

CO2-mediated liquid H2 storage is a promising technology; however, it typically requires additives such as bases, which increase both cost and energy consumption. Herein, a bimetallic Ru complex is fabricated that catalyzes reversible cycles of CO2 hydroge ...

ROYAL SOC CHEMISTRY2025

Multifunctional SnO2 QDs/MXene Heterostructures as Laminar Interlayers for Improved Polysulfide Conversion and Lithium Plating Behavior

Frank Nüesch, Mohammad Jafarpour, Shungui Deng

Poor cycling stability in lithium-sulfur (Li-S) batteries necessitates advanced electrode/electrolyte design and innovative interlayer architectures. Heterogeneous catalysis has emerged as a promising approach, leveraging the adsorption and catalytic perfo ...

SHANGHAI JIAO TONG UNIV PRESS2024

Swiss CAT plus , a Data-driven Infrastructure for Accelerated Catalysts Discovery and Optimization

Elisa Clerc, Urielle Marine Randrianarisoa, Nicolai Cramer, Pascal Miéville, Florian Patrick Marie Daniel De la Barre De Nanteuil, Edy Mariano, Keyan Michel Villat, Jean-Charles Louis André Cousty

The Catalysis Hub - Swiss CAT+, is a new infrastructure project funded by the ETH Domain, co -head-ed by EPFL and ETHZ. It offers the scientific community a unique integrated technology platform combining automated and high-throughput experimentation with ...

SWISS CHEMICAL SOC2023

Azido-alkynylation of alkenes through radical-polar crossover

Jérôme Waser, Julien Aymeric Borrel

We report an azido-alkynylation of alkenes allowing a straightforward access to homopropargylic azides by combining hypervalent iodine reagents and alkynyl-trifluoroborate salts. The design of a photocatalytic redox-neutral radical polar crossover process ...

2023

TaOx electron transport layers for CO2 reduction Si photocathodes

Raphaël François Lemerle, Elif Nur Dayi

Electron transport layers (ETLs) used as components of photocathodes for light-driven CO2 reduction (CO2R) in aqueous media should have good electronic transport, be stable under CO2R conditions, and, ideally, be catalytically inert for the competing hydro ...

Royal Society of Chemistry2023

Voltage-driven Reactivity of Liquid Ga and CuGa Nanoparticles for Electrocatalytic CO2 Reduction and Synthesis

Valery Okatenko

The rising atmospheric level of carbon dioxide, CO2, contributes to climate change and poses urgent need to find scalable solutions both to decrease its emissions and to be able to recycle it, if the goals of Paris Agreement to limit the temperature rise a ...

EPFL2023

Hydrogen Storage by Reduction of CO2 to Synthetic Hydrocarbons

Andreas Züttel, Wen Luo, Kun Zhao, Noris André Gallandat, Jie Zhang

The storage of renewable energy is crucial for the substitution of fossil fuels with renewable energy. Hydrogen is the first step in the conversion of electricity from renewable sources to an energy carrier. However, hydrogen is technically and economicall ...

2021

Asymmetric Elimination Reaction on Chiral Metal Surfaces

Harald Brune, Samuel Thomas Stolz

The production of enantiopure materials and molecules is of uttermost relevance in research and industry in numerous contexts, ranging from nonlinear optics to asymmetric synthesis. In the context of the latter, dehalogenation, which is an essential reacti ...

Wiley-V C H Verlag Gmbh2021

Ligand-mediated formation of Cu/metal oxide hybrid nanocrystals with tunable number of interfaces

Raffaella Buonsanti, Jan Vávra, Dragos-Constantin Stoian, James Richard Pankhurst, Seyedehbehnaz Varandili

Combining domains of different chemical nature within the same hybrid material through the formation of heterojunctions provides the opportunity to exploit the properties of each individual component within the same nano-object; furthermore, new synergisti ...

2020

Towards the Sarpagine-Ajmaline-Macroline Family of Indole Alkaloids: Enantioselective Synthesis of an N-Demethyl Alstolactone Diastereomer

Jieping Zhu, Qian Wang, Dylan Jean Robert Dagoneau

the strategy involving the use of functionalized tetrahydro-6H-cycloocta[b]indol-6-one is reported as a key intermediate for synthesis of members of the sarpagine-ajmaline-macroline family of monoterpene indole alkaloids. The desired tricycle was synthesiz ...

WILEY-V C H VERLAG GMBH2020

Mitigating voltage losses in photoelectrochemical cell scale-up

Sophia Haussener, Ronald Ramiro Gutierrez Perez

In solar water splitting, efforts in scaling up the photoelectrochemical cell beyond laboratory scale have started to attract significant attention. Several large-area devices have been demonstrated, but typically the efficiencies are much lower than their ...

ROYAL SOC CHEMISTRY2020

"Doubly Orthogonal" Labeling of Peptides and Proteins

Jérôme Waser, Beat Fierz, Nora Guidotti, Raphaël Michel Henri Simonet-Davin, Romain Gaëtan Tessier, Javier De Ceballos Cerrajeria

Herein, we report a cysteine bioconjugation methodology for the introduction of hypervalent iodine compounds onto biomolecules. Ethynylbenziodoxolones (EBXs) engage thiols in small organic molecules and cysteine-containing peptides and proteins in a fast a ...

2019

Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization, and Evaluation of Intracellular Glutathione S-Transferase Inhibition and Antiproliferative Activity

Paul Joseph Dyson, Tina Riedel, Emilia Paunescu

Four arene osmium complexes were prepared containing derivatives of ethacrynic acid, a potent inhibitor of glutathione Stransferases, either by direct coordination or via N- or P-donor ligands. The complexes were characterized by spectroscopic and analytic ...

American Chemical Society2016

TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations

Nicolai Cramer, Julia Pedroni

Monodentate TADDOL-derived phosphoramidites and phosphonites are versatile chiral ligands for enantio-selective Pd(0)-catalysed C-H functionalisations. They enable highly selective cyclisations to access a wide range of chiral carbo-and heterocycles. The h ...

Royal Society of Chemistry2015

The catalyzed hydrogen sorption mechanism in alkali alanates

Andreas Züttel, Philippe Mauron, Elsa Callini, Shunsuke Kato

The hydrogen sorption pathways of alkali alanates were analyzed and a mechanism for the catalytic hydrogen sorption was developed. Gibbs free energy values of selected intermediate steps were calculated based on experimentally determined thermodynamic data ...

Royal Society of Chemistry2015