Publication

A bimetallic ruthenium ethylene complex as a catalyst precursor for the Kharasch reaction

Kay Severin, Euro Solari, Laurent Quebatte
2005
Journal Articles

Abstract

A bimetallic complex, in which a RuCl2 (eta(2)C(2)H(4))(PCy3) fragment is connected via three chloro, bridges to a (eta(6)-p-cymene)RuCl2 fragment, has been synthesized and characterized by single-crystal X-ray crystallography. This complex was used to catalyze the atom transfer radical addition Of CCl4 and CHCl3 to olefins at temperatures between 0 and 40 degrees C. Turnover frequencies of up to 1550 h(-1) were observed, making the new complex one of the most active catalysts for this type of reaction described so far.

Official source

https://infoscience.epfl.ch/entities/publication/68f9ae02-d1b8-4266-9bd3-9892ddcb312b

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A bimetallic ruthenium ethylene complex as a catalyst precursor for the Kharasch reaction

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