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Pervaporation separation properties of water-butan-l-of binary mixtures were measured with the use of three supported liquid membranes at 37 C, namely PDMS, 1-ethenyl-3-ethyl-imidazolium hexafluorophosphate-PDMS, and tetrapropyl-ammonium tetracyanoborate-PDMS membranes. An ultrafiltration ceramic module from TiO2 with 60 nm pore size was used as a support. The diffusion coefficients of butan-1-ol in IL-PDMS were much higher than in PDMS only. However, the sorption isotherms were identical for all three measured membranes. Higher permeation flux and enrichment factors of butan-l-of in IL-PDMS membrane were probably caused by higher diffusion coefficient. The supported ionic liquid membranes were stable during all measurements.
Christian Heinis, Alexander Lund Nielsen, Manuel Leonardo Merz, Xinjian Ji, Ganesh Kumar Mothukuri, Anne Sofie Luise Zarda, Zsolt Bognár
Kumar Varoon Agrawal, Cédric Karel J Van Goethem