GasificationGasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed.
Thermochemical cycleThermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If work is partially used as an input, the resulting thermochemical cycle is defined as a hybrid one. This concept was first postulated by Funk and Reinstrom (1966) as a maximally efficient way to produce fuels (e.g.
Ethanol fuelEthanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline. Several common ethanol fuel mixtures are in use around the world. The use of pure hydrous or anhydrous ethanol in internal combustion engines (ICEs) is only possible if the engines are designed or modified for that purpose.
BiofuelBiofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. The climate change mitigation potential of biofuel varies considerably, from emission levels comparable to fossil fuels in some scenarios to negative emissions in others. Biofuels are mostly used for transportation, but can also be used for heating and electricity.
BioenergyBioenergy is energy made or generated from biomass, which consists of recently living (but now dead) organisms, mainly plants. Types of biomass commonly used for bioenergy include wood, food crops such as corn, energy crops and waste from forests, yards, or farms. The IPCC (Intergovernmental Panel on Climate Change) defines bioenergy as a renewable form of energy. Bioenergy can either mitigate (i.e. reduce) or increase greenhouse gas emissions. There is also agreement that local environmental impacts can be problematic.
Solar fuelA solar fuel is a synthetic chemical fuel produced from solar energy. Solar fuels can be produced through photochemical (i.e. activation of certain chemical reactions by photons), photobiological (i.e., artificial photosynthesis), and electrochemical reactions (i.e. using the electricity from solar panels to drive a chemical reaction). Solar fuels can also be produced by thermochemical reactions (i.e., through the use of solar heat supplied by concentrated solar thermal energy to drive a chemical reaction).
Waste-to-energyWaste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels. The first incinerator or "Destructor" was built in Nottingham, UK, in 1874 by Manlove, Alliott & Co.
Environmental scienceEnvironmental science is an interdisciplinary academic field that integrates physics, biology, and geography (including ecology, chemistry, plant science, zoology, mineralogy, oceanography, limnology, soil science, geology and physical geography, and atmospheric science) to the study of the environment, and the solution of environmental problems. Environmental science emerged from the fields of natural history and medicine during the Enlightenment. Today it provides an integrated, quantitative, and interdisciplinary approach to the study of environmental systems.
Synthetic fuelSynthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas. Common ways for refining synthetic fuels include the Fischer–Tropsch conversion, methanol to gasoline conversion, or direct coal liquefaction. The term 'synthetic fuel' or 'synfuel' has several different meanings and it may include different types of fuels.
Steam reformingSteam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is hydrogen production. The reaction is represented by this equilibrium: CH4 + H2O CO + 3 H2 The reaction is strongly endothermic (ΔHSR = 206 kJ/mol). Hydrogen produced by steam reforming is termed 'grey hydrogen' when the waste carbon monoxide is released to the atmosphere and 'blue hydrogen' when the carbon monoxide is (mostly) captured and stored geologically - see carbon capture and storage.
Coal gasificationIn industrial chemistry, coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (), carbon dioxide (), methane (), and water vapour ()—from coal and water, air and/or oxygen. Historically, coal was gasified to produce coal gas, also known as "town gas". Coal gas is combustible and was used for heating and municipal lighting, before the advent of large-scale extraction of natural gas from oil wells.
Second-generation biofuelsSecond-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel. First-generation biofuels are made from sugar-starch feedstocks (e.g., sugarcane and corn) and edible oil feedstocks (e.g., rapeseed and soybean oil), which are generally converted into bioethanol and biodiesel, respectively.
Water splittingWater splitting is the chemical reaction in which water is broken down into oxygen and hydrogen: 2 H2O → 2 H2 + O2 Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy, based on green hydrogen. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Electrolysis of water Electrolysis of water is the decomposition of water (H2O) into oxygen (O2) and hydrogen (H2) due to an electric current being passed through the water.
Environmental healthEnvironmental health is the branch of public health concerned with all aspects of the natural and built environment affecting human health. In order to effectively control factors that may affect health, the requirements that must be met in order to create a healthy environment must be determined. The major sub-disciplines of environmental health are environmental science, toxicology, environmental epidemiology, and environmental and occupational medicine.
Hydrogen productionHydrogen production is the family of industrial methods for generating hydrogen gas. As of 2020, the majority of hydrogen (~95%) is produced from fossil fuels by steam reforming of natural gas and other light hydrocarbons, partial oxidation of heavier hydrocarbons, and coal gasification. Other methods of hydrogen production include biomass gasification, methane pyrolysis, and electrolysis of water. Methane pyrolysis and water electrolysis can use any source of electricity including solar power.
Greenhouse gas emissionsGreenhouse gas emissions (abbreviated as GHG emissions) from human activities strengthen the greenhouse effect, contributing to climate change. Carbon dioxide (), from burning fossil fuels such as coal, oil, and natural gas, is one of the most important factors in causing climate change. The largest emitters are China followed by the US, although the United States has higher emissions per capita. The main producers fueling the emissions globally are large oil and gas companies.
Fuel cellA fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
Plasma gasificationPlasma gasification is an extreme thermal process using plasma which converts organic matter into a syngas (synthesis gas) which is primarily made up of hydrogen and carbon monoxide. A plasma torch powered by an electric arc is used to ionize gas and catalyze organic matter into syngas, with slag remaining as a byproduct. It is used commercially as a form of waste treatment, and has been tested for the gasification of refuse-derived fuel, biomass, industrial waste, hazardous waste, and solid hydrocarbons, such as coal, oil sands, petcoke and oil shale.
Integrated gasification combined cycleAn integrated gasification combined cycle (IGCC) is a technology using a high pressure gasifier to turn coal and other carbon based fuels into pressurized gas—synthesis gas (syngas). It can then remove impurities from the syngas prior to the electricity generation cycle. Some of these pollutants, such as sulfur, can be turned into re-usable byproducts through the Claus process. This results in lower emissions of sulfur dioxide, particulates, mercury, and in some cases carbon dioxide.
Thermal depolymerizationThermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalysed or un-catalysed and is distinct from other forms of depolymerisation which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy. For most polymers thermal depolymerisation is chaotic process, giving a mixture of volatile compounds.
