Rotational–vibrational spectroscopyRotational–vibrational spectroscopy is a branch of molecular spectroscopy concerned with infrared and Raman spectra of molecules in the gas phase. Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational) transitions. When such transitions emit or absorb photons (electromagnetic radiation), the frequency is proportional to the difference in energy levels and can be detected by certain kinds of spectroscopy.
Molecular vibrationA molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm−1 and wavelengths of approximately 30 to 3 μm. For a diatomic molecule A−B, the vibrational frequency in s−1 is given by , where k is the force constant in dyne/cm or erg/cm2 and μ is the reduced mass given by .
Rotational spectroscopyRotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy.
Rotational transitionIn quantum mechanics, a rotational transition is an abrupt change in angular momentum. Like all other properties of a quantum particle, angular momentum is quantized, meaning it can only equal certain discrete values, which correspond to different rotational energy states. When a particle loses angular momentum, it is said to have transitioned to a lower rotational energy state. Likewise, when a particle gains angular momentum, a positive rotational transition is said to have occurred.
Energy levelA quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules.
Stellar atmosphereThe stellar atmosphere is the outer region of the volume of a star, lying above the stellar core, radiation zone and convection zone. The stellar atmosphere is divided into several regions of distinct character: The photosphere, which is the atmosphere's lowest and coolest layer, is normally its only visible part. Light escaping from the surface of the star stems from this region and passes through the higher layers. The Sun's photosphere has a temperature in the range.
Magnitude (astronomy)In astronomy, magnitude is measure of the brightness of an object, usually in a defined passband. An imprecise but systematic determination of the magnitude of objects was introduced in ancient times by Hipparchus. Magnitude values do not have a unit. The scale is logarithmic and defined such that a magnitude 1 star is exactly 100 times brighter than a magnitude 6 star. Thus each step of one magnitude is times brighter than the magnitude 1 higher.
Selection ruleIn physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules, in atoms, in atomic nuclei, and so on. The selection rules may differ according to the technique used to observe the transition. The selection rule also plays a role in chemical reactions, where some are formally spin-forbidden reactions, that is, reactions where the spin state changes at least once from reactants to products.
PhotosphereThe photosphere is a star's outer shell from which light is radiated. The term itself is derived from Ancient Greek roots, φῶς, φωτός/phos, photos meaning "light" and σφαῖρα/sphaira meaning "sphere", in reference to it being a spherical surface that is perceived to emit light. It extends into a star's surface until the plasma becomes opaque, equivalent to an optical depth of approximately , or equivalently, a depth from which 50% of light will escape without being scattered.
Apparent magnitudeApparent magnitude (m) is a measure of the brightness of a star or other astronomical object. An object's apparent magnitude depends on its intrinsic luminosity, its distance, and any extinction of the object's light caused by interstellar dust along the line of sight to the observer. The word magnitude in astronomy, unless stated otherwise, usually refers to a celestial object's apparent magnitude. The magnitude scale dates back to the ancient Roman astronomer Claudius Ptolemy, whose star catalog listed stars from 1st magnitude (brightest) to 6th magnitude (dimmest).
Infrared astronomyInfrared astronomy is a sub-discipline of astronomy which specializes in the observation and analysis of astronomical objects using infrared (IR) radiation. The wavelength of infrared light ranges from 0.75 to 300 micrometers, and falls in between visible radiation, which ranges from 380 to 750 nanometers, and submillimeter waves. Infrared astronomy began in the 1830s, a few decades after the discovery of infrared light by William Herschel in 1800.
Limiting magnitudeIn astronomy, limiting magnitude is the faintest apparent magnitude of a celestial body that is detectable or detected by a given instrument. In some cases, limiting magnitude refers to the upper threshold of detection. In more formal uses, limiting magnitude is specified along with the strength of the signal (e.g., "10th magnitude at 20 sigma"). Sometimes limiting magnitude is qualified by the purpose of the instrument (e.g., "10th magnitude for photometry") This statement recognizes that a photometric detector can detect light far fainter than it can reliably measure.
Stellar classificationIn astronomy, stellar classification is the classification of stars based on their spectral characteristics. Electromagnetic radiation from the star is analyzed by splitting it with a prism or diffraction grating into a spectrum exhibiting the rainbow of colors interspersed with spectral lines. Each line indicates a particular chemical element or molecule, with the line strength indicating the abundance of that element. The strengths of the different spectral lines vary mainly due to the temperature of the photosphere, although in some cases there are true abundance differences.
Electromagnetic absorption by waterThe absorption of electromagnetic radiation by water depends on the state of the water. The absorption in the gas phase occurs in three regions of the spectrum. Rotational transitions are responsible for absorption in the microwave and far-infrared, vibrational transitions in the mid-infrared and near-infrared. Vibrational bands have rotational fine structure. Electronic transitions occur in the vacuum ultraviolet regions. Liquid water has no rotational spectrum but does absorb in the microwave region.
Ground stateThe ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states.
Infrared spectroscopyInfrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum.
Submillimetre astronomySubmillimetre astronomy or submillimeter astronomy (see spelling differences) is the branch of observational astronomy that is conducted at submillimetre wavelengths (i.e., terahertz radiation) of the electromagnetic spectrum. Astronomers place the submillimetre waveband between the far-infrared and microwave wavebands, typically taken to be between a few hundred micrometres and a millimetre. It is still common in submillimetre astronomy to quote wavelengths in 'microns', the old name for micrometre.
Degenerate energy levelsIn quantum mechanics, an energy level is degenerate if it corresponds to two or more different measurable states of a quantum system. Conversely, two or more different states of a quantum mechanical system are said to be degenerate if they give the same value of energy upon measurement. The number of different states corresponding to a particular energy level is known as the degree of degeneracy (or simply the degeneracy) of the level.
Circumstellar dustCircumstellar dust is cosmic dust around a star. It can be in the form of a spherical shell or a disc, e.g. an accretion disk. Circumstellar dust can be responsible for significant extinction and is usually the source of an infrared excess for stars that have it. For some evolved stars on the asymptotic giant branch, the dust is composed of silicate emissions while others contain the presence of other dust components. According to a study, it is still uncertain whether the dust is a result of crystalline silicate or polycyclic aromatic hydrocarbon.
WaterWater is an inorganic compound with the chemical formula . It is a transparent, tasteless, odorless, and nearly colorless chemical substance, and it is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food energy, or organic micronutrients. Its chemical formula, , indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds.
